Hetero Diels–Alder Reaction and Ene Reaction of Acylnitroso Species in situ Generated by Hypoiodite Catalysis; European Journal of Organic Chemistry; Vol. 2018, iss. 45
| Parent link: | European Journal of Organic Chemistry Vol. 2018, iss. 45.— 2018.— [P. 6199-6203] |
|---|---|
| Autor corporatiu: | |
| Altres autors: | , , , , , , |
| Sumari: | Title screen As a first non?metal?catalyzed oxidation for the in situ generation of acylnitroso species, we describe the hypoiodite catalysis using tetra?n?butylammonium iodide as precatalyst with tert?butyl hydroperoxide or hydrogen peroxide as a terminal oxidant. This method can be applied to hetero Diels–Alder (HDA) reactions with dienes and ene reactions with alkenes. Furthermore, the conversions of the representative HDA adduct to nitrone and 2?amino alcohols were demonstrated. Compared with previous metal?catalyzed oxidation methods, this work provides a more efficient and environmentally friendly procedure. Режим доступа: по договору с организацией-держателем ресурса |
| Idioma: | anglès |
| Publicat: |
2018
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| Matèries: | |
| Accés en línia: | https://doi.org/10.1002/ejoc.201801340 |
| Format: | Electrònic Capítol de llibre |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=660275 |
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| 200 | 1 | |a Hetero Diels–Alder Reaction and Ene Reaction of Acylnitroso Species in situ Generated by Hypoiodite Catalysis |f S. Uraoka, I. Shinohara, H. Shimizu [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: 19 tit.] | ||
| 330 | |a As a first non?metal?catalyzed oxidation for the in situ generation of acylnitroso species, we describe the hypoiodite catalysis using tetra?n?butylammonium iodide as precatalyst with tert?butyl hydroperoxide or hydrogen peroxide as a terminal oxidant. This method can be applied to hetero Diels–Alder (HDA) reactions with dienes and ene reactions with alkenes. Furthermore, the conversions of the representative HDA adduct to nitrone and 2?amino alcohols were demonstrated. Compared with previous metal?catalyzed oxidation methods, this work provides a more efficient and environmentally friendly procedure. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t European Journal of Organic Chemistry | ||
| 463 | |t Vol. 2018, iss. 45 |v [P. 6199-6203] |d 2018 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a acylnitroso | |
| 610 | 1 | |a catalysis | |
| 610 | 1 | |a cycloaddition | |
| 610 | 1 | |a ene reaction iodine | |
| 610 | 1 | |a катализ | |
| 610 | 1 | |a циклоприсоединение | |
| 701 | 1 | |a Uraoka |b S. |g Saki | |
| 701 | 1 | |a Shinohara |b I. |g Ikumi | |
| 701 | 1 | |a Shimizu |b H. |g Hisato | |
| 701 | 1 | |a Noguchi |b K. |g Keiichi | |
| 701 | 1 | |a Yoshimura |b A. |c chemical engineer |c Professor of Tomsk Polytechnic University |f 1981- |g Akira |3 (RuTPU)RU\TPU\pers\39852 | |
| 701 | 1 | |a Zhdankin |b V. V. |c химик |c Professor of Tomsk Polytechnic University, Doctor of chemical sciences |f 1956- |g Viktor Vladimirovich |3 (RuTPU)RU\TPU\pers\35758 | |
| 701 | 1 | |a Saito |b A. |g Akio | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Исследовательская школа химических и биомедицинских технологий (ИШХБМТ) |c (2017- ) |3 (RuTPU)RU\TPU\col\23537 |
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| 856 | 4 | |u https://doi.org/10.1002/ejoc.201801340 | |
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