Hetero Diels–Alder Reaction and Ene Reaction of Acylnitroso Species in situ Generated by Hypoiodite Catalysis; European Journal of Organic Chemistry; Vol. 2018, iss. 45

Hetero Diels–Alder Reaction and Ene Reaction of Acylnitroso Species in situ Generated by Hypoiodite Catalysis

Λεπτομέρειες βιβλιογραφικής εγγραφής
Parent link:European Journal of Organic Chemistry
Vol. 2018, iss. 45.— 2018.— [P. 6199-6203]
Συγγραφή απο Οργανισμό/Αρχή: Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий (ИШХБМТ)
Άλλοι συγγραφείς: Uraoka S. Saki, Shinohara I. Ikumi, Shimizu H. Hisato, Noguchi K. Keiichi, Yoshimura A. Akira, Zhdankin V. V. Viktor Vladimirovich, Saito A. Akio
Περίληψη:Title screen
As a first non?metal?catalyzed oxidation for the in situ generation of acylnitroso species, we describe the hypoiodite catalysis using tetra?n?butylammonium iodide as precatalyst with tert?butyl hydroperoxide or hydrogen peroxide as a terminal oxidant. This method can be applied to hetero Diels–Alder (HDA) reactions with dienes and ene reactions with alkenes. Furthermore, the conversions of the representative HDA adduct to nitrone and 2?amino alcohols were demonstrated. Compared with previous metal?catalyzed oxidation methods, this work provides a more efficient and environmentally friendly procedure.
Режим доступа: по договору с организацией-держателем ресурса
Γλώσσα:Αγγλικά
Έκδοση: 2018
Θέματα:
электронный ресурс
труды учёных ТПУ
acylnitroso
catalysis
cycloaddition
ene reaction iodine
катализ
циклоприсоединение
Διαθέσιμο Online:https://doi.org/10.1002/ejoc.201801340
Μορφή: Ηλεκτρονική πηγή Κεφάλαιο βιβλίου
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=660275
Περιγραφή
Περίληψη:Title screen
As a first non?metal?catalyzed oxidation for the in situ generation of acylnitroso species, we describe the hypoiodite catalysis using tetra?n?butylammonium iodide as precatalyst with tert?butyl hydroperoxide or hydrogen peroxide as a terminal oxidant. This method can be applied to hetero Diels–Alder (HDA) reactions with dienes and ene reactions with alkenes. Furthermore, the conversions of the representative HDA adduct to nitrone and 2?amino alcohols were demonstrated. Compared with previous metal?catalyzed oxidation methods, this work provides a more efficient and environmentally friendly procedure.
Режим доступа: по договору с организацией-держателем ресурса
DOI:10.1002/ejoc.201801340

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