Synthesis of β-oxopropylcarbamates in a recyclable AgBr/ionic liquid catalytic system: An efficient assembly of CO2 under ambient pressure
| Parent link: | Journal of CO2 Utilization Vol. 27.— 2018.— [P. 217-222] |
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| Altres autors: | , , , , , , |
| Sumari: | Title screen A green and recyclable catalytic system based on AgBr and an ionic liquid (IL) was developed for the three-component coupling reaction of propargylic alcohols, secondary amines and carbon dioxide (CO2). A series of target carbamates, especially those generated from challenging substrates, could be obtained smoothly at atmospheric CO2 pressure in a straightforward one-pot process. Moreover, the catalyst loading reached the lowermost level ever reported. Particularly, this catalytic system exhibited robust constancy and could be reused at least 5 times with retention of high catalytic activity. It is worth noting that this is the first catalytic system which could be recycled successfully for this reaction. Режим доступа: по договору с организацией-держателем ресурса |
| Idioma: | anglès |
| Publicat: |
2018
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| Matèries: | |
| Accés en línia: | https://doi.org/10.1016/j.jcou.2018.07.021 |
| Format: | Electrònic Capítol de llibre |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=660130 |