Preparation and structure of phenolic aryliodonium salts

Preparation and structure of phenolic aryliodonium salts

Detalhes bibliográficos
Parent link:Chemical Communications
Vol. 54, iss. 73.— 2018.— [P. 10363-10366]
Autor Corporativo: Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий (ИШХБМТ)
Outros Autores: Yoshimura A. Akira, Shea M. T. Michael T., Guselnikova O. A. Olga Andreevna, Postnikov P. S. Pavel Sergeevich, Rohde G. T. Gregory T., Saito A. Akio, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Немыкин В. Н. Виктор Николаевич, Zhdankin V. V. Viktor V.
Resumo:Title screen
Phenol based aryliodonium salts were prepared by the reaction of [hydroxy(tosyloxy)iodo]arenes with aryl silyl ethers in the presence of trifluoromethanesulfonic acid. Structures of several aryliodonium salts with the hydroxy group in the para-position of the phenyl ring were established by single crystal X-ray crystallography. Under basic conditions, 4-hydroxyphenyl(phenyl)iodonium salts form a dimeric hypervalent iodine(III) complex, oxyphenyl(phenyl)iodonium ylidic salt, the solid structure of which was confirmed by X-ray crystallography. Phenolic iodonium salts are potentially useful phenol transfer reagents in reactions with various anionic nucleophiles.
Режим доступа: по договору с организацией-держателем ресурса
Publicado em: 2018
Assuntos:
электронный ресурс
труды учёных ТПУ
salt
crystallography
phenol
iodine
соли
кислоты
фенолы
нуклеофилы
монокристаллы
рентгеновская кристаллография
йод
эфиры
Acesso em linha:http://dx.doi.org/10.1039/C8CC06211K
Formato: Recurso Electrónico Capítulo de Livro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=659709

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