Preparation and structure of phenolic aryliodonium salts; Chemical Communications; Vol. 54, iss. 73

Preparation and structure of phenolic aryliodonium salts; Chemical Communications; Vol. 54, iss. 73

Bibliografske podrobnosti
Parent link:	Chemical Communications Vol. 54, iss. 73.— 2018.— [P. 10363-10366]
Korporativna značnica:	Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий (ИШХБМТ)
Drugi avtorji:	Yoshimura A. Akira, Shea M. T. Michael T., Guselnikova O. A. Olga Andreevna, Postnikov P. S. Pavel Sergeevich, Rohde G. T. Gregory T., Saito A. Akio, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Немыкин В. Н. Виктор Николаевич, Zhdankin V. V. Viktor V.
Izvleček:	Title screen Phenol based aryliodonium salts were prepared by the reaction of [hydroxy(tosyloxy)iodo]arenes with aryl silyl ethers in the presence of trifluoromethanesulfonic acid. Structures of several aryliodonium salts with the hydroxy group in the para-position of the phenyl ring were established by single crystal X-ray crystallography. Under basic conditions, 4-hydroxyphenyl(phenyl)iodonium salts form a dimeric hypervalent iodine(III) complex, oxyphenyl(phenyl)iodonium ylidic salt, the solid structure of which was confirmed by X-ray crystallography. Phenolic iodonium salts are potentially useful phenol transfer reagents in reactions with various anionic nucleophiles. Режим доступа: по договору с организацией-держателем ресурса
Jezik:	angleščina
Izdano:	2018
Teme:	электронный ресурс труды учёных ТПУ salt crystallography phenol iodine соли кислоты фенолы нуклеофилы монокристаллы рентгеновская кристаллография йод эфиры
Online dostop:	http://dx.doi.org/10.1039/C8CC06211K
Format:	Elektronski Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=659709

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