Preparation and structure of phenolic aryliodonium salts

Preparation and structure of phenolic aryliodonium salts

Bibliographic Details
Parent link:	Chemical Communications Vol. 54, iss. 73.— 2018.— [P. 10363-10366]
Corporate Author:	Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий (ИШХБМТ)
Other Authors:	Yoshimura A. Akira, Shea M. T. Michael T., Guselnikova O. A. Olga Andreevna, Postnikov P. S. Pavel Sergeevich, Rohde G. T. Gregory T., Saito A. Akio, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Немыкин В. Н. Виктор Николаевич, Zhdankin V. V. Viktor V.
Summary:	Title screen Phenol based aryliodonium salts were prepared by the reaction of [hydroxy(tosyloxy)iodo]arenes with aryl silyl ethers in the presence of trifluoromethanesulfonic acid. Structures of several aryliodonium salts with the hydroxy group in the para-position of the phenyl ring were established by single crystal X-ray crystallography. Under basic conditions, 4-hydroxyphenyl(phenyl)iodonium salts form a dimeric hypervalent iodine(III) complex, oxyphenyl(phenyl)iodonium ylidic salt, the solid structure of which was confirmed by X-ray crystallography. Phenolic iodonium salts are potentially useful phenol transfer reagents in reactions with various anionic nucleophiles. Режим доступа: по договору с организацией-держателем ресурса
Published:	2018
Subjects:	электронный ресурс труды учёных ТПУ salt crystallography phenol iodine соли кислоты фенолы нуклеофилы монокристаллы рентгеновская кристаллография йод эфиры
Online Access:	http://dx.doi.org/10.1039/C8CC06211K
Format:	Electronic Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=659709

Internet

http://dx.doi.org/10.1039/C8CC06211K