Preparation and structure of phenolic aryliodonium salts; Chemical Communications; Vol. 54, iss. 73
| Parent link: | Chemical Communications Vol. 54, iss. 73.— 2018.— [P. 10363-10366] |
|---|---|
| مؤلف مشترك: | |
| مؤلفون آخرون: | , , , , , , , , |
| الملخص: | Title screen Phenol based aryliodonium salts were prepared by the reaction of [hydroxy(tosyloxy)iodo]arenes with aryl silyl ethers in the presence of trifluoromethanesulfonic acid. Structures of several aryliodonium salts with the hydroxy group in the para-position of the phenyl ring were established by single crystal X-ray crystallography. Under basic conditions, 4-hydroxyphenyl(phenyl)iodonium salts form a dimeric hypervalent iodine(III) complex, oxyphenyl(phenyl)iodonium ylidic salt, the solid structure of which was confirmed by X-ray crystallography. Phenolic iodonium salts are potentially useful phenol transfer reagents in reactions with various anionic nucleophiles. Режим доступа: по договору с организацией-держателем ресурса |
| اللغة: | الإنجليزية |
| منشور في: |
2018
|
| الموضوعات: | |
| الوصول للمادة أونلاين: | http://dx.doi.org/10.1039/C8CC06211K |
| التنسيق: | الكتروني فصل الكتاب |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=659709 |
MARC
| LEADER | 00000naa0a2200000 4500 | ||
|---|---|---|---|
| 001 | 659709 | ||
| 005 | 20250522111610.0 | ||
| 035 | |a (RuTPU)RU\TPU\network\28452 | ||
| 035 | |a RU\TPU\network\17068 | ||
| 090 | |a 659709 | ||
| 100 | |a 20190322d2018 k||y0rusy50 ba | ||
| 101 | 0 | |a eng | |
| 102 | |a GB | ||
| 135 | |a drcn ---uucaa | ||
| 181 | 0 | |a i | |
| 182 | 0 | |a b | |
| 200 | 1 | |a Preparation and structure of phenolic aryliodonium salts |f A. Yoshimura [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 330 | |a Phenol based aryliodonium salts were prepared by the reaction of [hydroxy(tosyloxy)iodo]arenes with aryl silyl ethers in the presence of trifluoromethanesulfonic acid. Structures of several aryliodonium salts with the hydroxy group in the para-position of the phenyl ring were established by single crystal X-ray crystallography. Under basic conditions, 4-hydroxyphenyl(phenyl)iodonium salts form a dimeric hypervalent iodine(III) complex, oxyphenyl(phenyl)iodonium ylidic salt, the solid structure of which was confirmed by X-ray crystallography. Phenolic iodonium salts are potentially useful phenol transfer reagents in reactions with various anionic nucleophiles. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Chemical Communications | ||
| 463 | |t Vol. 54, iss. 73 |v [P. 10363-10366] |d 2018 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a salt | |
| 610 | 1 | |a crystallography | |
| 610 | 1 | |a phenol | |
| 610 | 1 | |a iodine | |
| 610 | 1 | |a соли | |
| 610 | 1 | |a кислоты | |
| 610 | 1 | |a фенолы | |
| 610 | 1 | |a нуклеофилы | |
| 610 | 1 | |a монокристаллы | |
| 610 | 1 | |a рентгеновская кристаллография | |
| 610 | 1 | |a йод | |
| 610 | 1 | |a эфиры | |
| 701 | 1 | |a Yoshimura |b A. |c chemical engineer |c Professor of Tomsk Polytechnic University |f 1981- |g Akira |3 (RuTPU)RU\TPU\pers\39852 | |
| 701 | 1 | |a Shea |b M. T. |g Michael T. | |
| 701 | 1 | |a Guselnikova |b O. A. |c chemist |c Researcher at Tomsk Polytechnic University, Candidate of Chemical Sciences |f 1992- |g Olga Andreevna |3 (RuTPU)RU\TPU\pers\34478 |9 17861 | |
| 701 | 1 | |a Postnikov |b P. S. |c organic chemist |c Associate Professor of Tomsk Polytechnic University, Candidate of chemical sciences |f 1984- |g Pavel Sergeevich |3 (RuTPU)RU\TPU\pers\31287 |9 15465 | |
| 701 | 1 | |a Rohde |b G. T. |g Gregory T. | |
| 701 | 1 | |a Saito |b A. |g Akio | |
| 701 | 1 | |a Yusubov |b M. S. |c chemist |c Professor of Tomsk Polytechnic University, Doctor of chemical sciences |f 1961- |g Mekhman Suleiman-Ogly (Suleimanovich) |3 (RuTPU)RU\TPU\pers\31833 | |
| 701 | 1 | |a Немыкин |b В. Н. |g Виктор Николаевич | |
| 701 | 1 | |a Zhdankin |b V. V. |g Viktor V. | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Исследовательская школа химических и биомедицинских технологий (ИШХБМТ) |c (2017- ) |3 (RuTPU)RU\TPU\col\23537 |
| 801 | 2 | |a RU |b 63413507 |c 20190328 |g RCR | |
| 850 | |a 63413507 | ||
| 856 | 4 | |u http://dx.doi.org/10.1039/C8CC06211K | |
| 942 | |c CF | ||