Verdazyl Radical Building Blocks: Synthesis, Structure, and Sonogashira Cross-Coupling Reactions; European Journal of Organic Chemistry; Vol. 2018, iss. 34
| Parent link: | European Journal of Organic Chemistry Vol. 2018, iss. 34.— 2018.— [P. 4802-4811] |
|---|---|
| 団体著者: | Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий (ИШХБМТ) |
| その他の著者: | Petunin P. V. Pavel Vasilievich, Martynko E. A. Ekaterina Andreevna, Trusova M. E. Marina Evgenievna, Kazantsev M. S. Maksim Sergeevich, Rybalova T. V. Tatjyana Valerjevna, Valiev R. R. Rashid Rinatovich, Uvarov M. N. Mikhail Nikolaevich, Mostovich E. A. Evgeny Alekseevich, Postnikov P. S. Pavel Sergeevich |
| 要約: | Title screen A general and effective method for the synthesis of 3?phenylveradzyl radicals bearing a variety of iodophenyl substituents has been developed. The synthesized radicals have been characterized by ESR, UV/Vis spectroscopy, and cyclic voltammetry. Structures of biphenyl?substituted radicals have been solved by X?ray crystal structure analysis. The synthesized iodoverdazyls are applicable in the Sonogashira coupling reaction for the preparation of a wide range of ethynyl derivatives. Both N?2 and C?6 substituents were functionalized through Sonogashira coupling. Режим доступа: по договору с организацией-держателем ресурса |
| 言語: | 英語 |
| 出版事項: |
2018
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| 主題: | |
| オンライン・アクセス: | https://doi.org/10.1002/ejoc.201701783 |
| フォーマット: | 電子媒体 図書の章 |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=659475 |
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