Verdazyl Radical Building Blocks: Synthesis, Structure, and Sonogashira Cross-Coupling Reactions

Verdazyl Radical Building Blocks: Synthesis, Structure, and Sonogashira Cross-Coupling Reactions

Bibliographic Details
Parent link:European Journal of Organic Chemistry
Vol. 2018, iss. 34.— 2018.— [P. 4802-4811]
Corporate Author: Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий (ИШХБМТ)
Other Authors: Petunin P. V. Pavel Vasilievich, Martynko E. A. Ekaterina Andreevna, Trusova M. E. Marina Evgenievna, Kazantsev M. S. Maksim Sergeevich, Rybalova T. V. Tatjyana Valerjevna, Valiev R. R. Rashid Rinatovich, Uvarov M. N. Mikhail Nikolaevich, Mostovich E. A. Evgeny Alekseevich, Postnikov P. S. Pavel Sergeevich
Summary:Title screen
A general and effective method for the synthesis of 3?phenylveradzyl radicals bearing a variety of iodophenyl substituents has been developed. The synthesized radicals have been characterized by ESR, UV/Vis spectroscopy, and cyclic voltammetry. Structures of biphenyl?substituted radicals have been solved by X?ray crystal structure analysis. The synthesized iodoverdazyls are applicable in the Sonogashira coupling reaction for the preparation of a wide range of ethynyl derivatives. Both N?2 and C?6 substituents were functionalized through Sonogashira coupling.
Режим доступа: по договору с организацией-держателем ресурса
Language:English
Published: 2018
Subjects:
электронный ресурс
труды учёных ТПУ
verdazyl radicals
nitrogen heterocycles
cross‐coupling
density functional calculations
вердазильные радикалы
гетероциклы
кросс-средства
расчеты
Online Access:https://doi.org/10.1002/ejoc.201701783
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=659475

Internet

https://doi.org/10.1002/ejoc.201701783

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