Verdazyl Radical Building Blocks: Synthesis, Structure, and Sonogashira Cross-Coupling Reactions; European Journal of Organic Chemistry; Vol. 2018, iss. 34

Verdazyl Radical Building Blocks: Synthesis, Structure, and Sonogashira Cross-Coupling Reactions; European Journal of Organic Chemistry; Vol. 2018, iss. 34

Detalhes bibliográficos
Parent link:	European Journal of Organic Chemistry Vol. 2018, iss. 34.— 2018.— [P. 4802-4811]
Autor Corporativo:	Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий (ИШХБМТ)
Outros Autores:	Petunin P. V. Pavel Vasilievich, Martynko E. A. Ekaterina Andreevna, Trusova M. E. Marina Evgenievna, Kazantsev M. S. Maksim Sergeevich, Rybalova T. V. Tatjyana Valerjevna, Valiev R. R. Rashid Rinatovich, Uvarov M. N. Mikhail Nikolaevich, Mostovich E. A. Evgeny Alekseevich, Postnikov P. S. Pavel Sergeevich
Resumo:	Title screen A general and effective method for the synthesis of 3?phenylveradzyl radicals bearing a variety of iodophenyl substituents has been developed. The synthesized radicals have been characterized by ESR, UV/Vis spectroscopy, and cyclic voltammetry. Structures of biphenyl?substituted radicals have been solved by X?ray crystal structure analysis. The synthesized iodoverdazyls are applicable in the Sonogashira coupling reaction for the preparation of a wide range of ethynyl derivatives. Both N?2 and C?6 substituents were functionalized through Sonogashira coupling. Режим доступа: по договору с организацией-держателем ресурса
Idioma:	inglês
Publicado em:	2018
Assuntos:	электронный ресурс труды учёных ТПУ verdazyl radicals nitrogen heterocycles cross‐coupling density functional calculations вердазильные радикалы гетероциклы кросс-средства расчеты
Acesso em linha:	https://doi.org/10.1002/ejoc.201701783
Formato:	Recurso Eletrônico Capítulo de Livro
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=659475

Internet

https://doi.org/10.1002/ejoc.201701783