Verdazyl Radical Building Blocks: Synthesis, Structure, and Sonogashira Cross-Coupling Reactions
| Parent link: | European Journal of Organic Chemistry Vol. 2018, iss. 34.— 2018.— [P. 4802-4811] |
|---|---|
| Korporativní autor: | |
| Další autoři: | , , , , , , , , |
| Shrnutí: | Title screen A general and effective method for the synthesis of 3?phenylveradzyl radicals bearing a variety of iodophenyl substituents has been developed. The synthesized radicals have been characterized by ESR, UV/Vis spectroscopy, and cyclic voltammetry. Structures of biphenyl?substituted radicals have been solved by X?ray crystal structure analysis. The synthesized iodoverdazyls are applicable in the Sonogashira coupling reaction for the preparation of a wide range of ethynyl derivatives. Both N?2 and C?6 substituents were functionalized through Sonogashira coupling. Режим доступа: по договору с организацией-держателем ресурса |
| Jazyk: | angličtina |
| Vydáno: |
2018
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| Témata: | |
| On-line přístup: | https://doi.org/10.1002/ejoc.201701783 |
| Médium: | Elektronický zdroj Kapitola |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=659475 |
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| 200 | 1 | |a Verdazyl Radical Building Blocks: Synthesis, Structure, and Sonogashira Cross-Coupling Reactions |f P. V. Petunin [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: 37 tit.] | ||
| 330 | |a A general and effective method for the synthesis of 3?phenylveradzyl radicals bearing a variety of iodophenyl substituents has been developed. The synthesized radicals have been characterized by ESR, UV/Vis spectroscopy, and cyclic voltammetry. Structures of biphenyl?substituted radicals have been solved by X?ray crystal structure analysis. The synthesized iodoverdazyls are applicable in the Sonogashira coupling reaction for the preparation of a wide range of ethynyl derivatives. Both N?2 and C?6 substituents were functionalized through Sonogashira coupling. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t European Journal of Organic Chemistry | ||
| 463 | |t Vol. 2018, iss. 34 |v [P. 4802-4811] |d 2018 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a verdazyl radicals | |
| 610 | 1 | |a nitrogen heterocycles | |
| 610 | 1 | |a cross‐coupling | |
| 610 | 1 | |a density functional calculations | |
| 610 | 1 | |a вердазильные радикалы | |
| 610 | 1 | |a гетероциклы | |
| 610 | 1 | |a кросс-средства | |
| 610 | 1 | |a расчеты | |
| 701 | 1 | |a Petunin |b P. V. |c chemist |c Associate Professor of Tomsk Polytechnic University, Candidate of Chemical Sciences |f 1982- |g Pavel Vasilievich |3 (RuTPU)RU\TPU\pers\36904 |9 19933 | |
| 701 | 1 | |a Martynko |b E. A. |g Ekaterina Andreevna | |
| 701 | 1 | |a Trusova |b M. E. |c organic chemist |c Associate professor of Tomsk Polytechnic University, Candidate of chemical sciences |f 1982- |g Marina Evgenievna |3 (RuTPU)RU\TPU\pers\31823 |9 15918 | |
| 701 | 1 | |a Kazantsev |b M. S. |g Maksim Sergeevich | |
| 701 | 1 | |a Rybalova |b T. V. |g Tatjyana Valerjevna | |
| 701 | 1 | |a Valiev |b R. R. |c chemist |c Assistant of Tomsk Polytechnic University |f 1983- |g Rashid Rinatovich |3 (RuTPU)RU\TPU\pers\34114 | |
| 701 | 1 | |a Uvarov |b M. N. |g Mikhail Nikolaevich | |
| 701 | 1 | |a Mostovich |b E. A. |g Evgeny Alekseevich | |
| 701 | 1 | |a Postnikov |b P. S. |c organic chemist |c Associate Professor of Tomsk Polytechnic University, Candidate of chemical sciences |f 1984- |g Pavel Sergeevich |3 (RuTPU)RU\TPU\pers\31287 |9 15465 | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Исследовательская школа химических и биомедицинских технологий (ИШХБМТ) |c (2017- ) |3 (RuTPU)RU\TPU\col\23537 |
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