Synthesis and Characterization of Barium Hexafluoridoosmates

Bibliografische gegevens
Parent link:Crystals
Vol. 8, iss. 1.— 2018.— [11, 10 p.]
Coauteur: Национальный исследовательский Томский политехнический университет Инженерная школа ядерных технологий Отделение ядерно-топливного цикла
Andere auteurs: Ivlev S. I. Sergey Ivanovich, Karttunen A. J. Antti, Buchner M. R. Magnus, Ostvald R. V. Roman Vyacheslavovich, Kraus F. Florian
Samenvatting:Title screen
Two barium hexafluoridoosmates, Ba(OsF6)2 and BaOsF6, were synthesized and were characterized for the first time using X-ray powder and single crystal diffraction, IR spectroscopy, as well as NMR spectroscopy in anhydrous hydrogen fluoride. Ba(OsF6)2 crystallizes in the space group type P21/c with the cell parameters a = 6.4599(4), b = 10.7931(8), c = 14.7476(10) Å, β = 115.195(5)°, V = 930.42(12) Å3, Z = 4 at 293 K. BaOsF6crystallizes in the space group type R 3¯ with the cell parameters a = 7.3286(10), c = 7.2658(15) Å, V = 337.95(12) Å3, Z = 3 at 100 K. Additionally, we have obtained the compounds Ba(OsF6)2∙3BrF3, Ba(OsF6)2∙HF, Ba(OsF6)2∙6H2O from the respective solvents, and Ba(OsF6)2.
Gepubliceerd in: 2018
Onderwerpen:
Online toegang:https://doi.org/10.3390/cryst8010011
Formaat: Elektronisch Hoofdstuk
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=658228

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