Synthesis and Characterization of Barium Hexafluoridoosmates

Synthesis and Characterization of Barium Hexafluoridoosmates

Bibliographic Details
Parent link:	Crystals Vol. 8, iss. 1.— 2018.— [11, 10 p.]
Corporate Author:	Национальный исследовательский Томский политехнический университет Инженерная школа ядерных технологий Отделение ядерно-топливного цикла
Other Authors:	Ivlev S. I. Sergey Ivanovich, Karttunen A. J. Antti, Buchner M. R. Magnus, Ostvald R. V. Roman Vyacheslavovich, Kraus F. Florian
Summary:	Title screen Two barium hexafluoridoosmates, Ba(OsF6)2 and BaOsF6, were synthesized and were characterized for the first time using X-ray powder and single crystal diffraction, IR spectroscopy, as well as NMR spectroscopy in anhydrous hydrogen fluoride. Ba(OsF6)2 crystallizes in the space group type P21/c with the cell parameters a = 6.4599(4), b = 10.7931(8), c = 14.7476(10) Å, β = 115.195(5)°, V = 930.42(12) Å3, Z = 4 at 293 K. BaOsF6crystallizes in the space group type R 3¯ with the cell parameters a = 7.3286(10), c = 7.2658(15) Å, V = 337.95(12) Å3, Z = 3 at 100 K. Additionally, we have obtained the compounds Ba(OsF6)2∙3BrF3, Ba(OsF6)2∙HF, Ba(OsF6)2∙6H2O from the respective solvents, and Ba(OsF6)2.
Published:	2018
Subjects:	труды учёных ТПУ электронный ресурс осмий фториды трифторид брома кристаллические структуры osmium fluorides bromine trifluoride crystal structure
Online Access:	https://doi.org/10.3390/cryst8010011
Format:	Electronic Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=658228

Internet

https://doi.org/10.3390/cryst8010011