Synthesis and Characterization of Barium Hexafluoridoosmates
| Parent link: | Crystals Vol. 8, iss. 1.— 2018.— [11, 10 p.] |
|---|---|
| Corporate Author: | |
| Other Authors: | , , , , |
| Summary: | Title screen Two barium hexafluoridoosmates, Ba(OsF6)2 and BaOsF6, were synthesized and were characterized for the first time using X-ray powder and single crystal diffraction, IR spectroscopy, as well as NMR spectroscopy in anhydrous hydrogen fluoride. Ba(OsF6)2 crystallizes in the space group type P21/c with the cell parameters a = 6.4599(4), b = 10.7931(8), c = 14.7476(10) Å, β = 115.195(5)°, V = 930.42(12) Å3, Z = 4 at 293 K. BaOsF6crystallizes in the space group type R 3¯ with the cell parameters a = 7.3286(10), c = 7.2658(15) Å, V = 337.95(12) Å3, Z = 3 at 100 K. Additionally, we have obtained the compounds Ba(OsF6)2∙3BrF3, Ba(OsF6)2∙HF, Ba(OsF6)2∙6H2O from the respective solvents, and Ba(OsF6)2. |
| Language: | English |
| Published: |
2018
|
| Subjects: | |
| Online Access: | https://doi.org/10.3390/cryst8010011 |
| Format: | Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=658228 |
MARC
| LEADER | 00000naa0a2200000 4500 | ||
|---|---|---|---|
| 001 | 658228 | ||
| 005 | 20250919160054.0 | ||
| 035 | |a (RuTPU)RU\TPU\network\25552 | ||
| 035 | |a RU\TPU\network\16764 | ||
| 090 | |a 658228 | ||
| 100 | |a 20180705d2018 k||y0rusy50 ba | ||
| 101 | 0 | |a eng | |
| 102 | |a CH | ||
| 135 | |a drcn ---uucaa | ||
| 181 | 0 | |a i | |
| 182 | 0 | |a b | |
| 200 | 1 | |a Synthesis and Characterization of Barium Hexafluoridoosmates |f S. I. Ivlev [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: 52 tit.] | ||
| 330 | |a Two barium hexafluoridoosmates, Ba(OsF6)2 and BaOsF6, were synthesized and were characterized for the first time using X-ray powder and single crystal diffraction, IR spectroscopy, as well as NMR spectroscopy in anhydrous hydrogen fluoride. Ba(OsF6)2 crystallizes in the space group type P21/c with the cell parameters a = 6.4599(4), b = 10.7931(8), c = 14.7476(10) Å, β = 115.195(5)°, V = 930.42(12) Å3, Z = 4 at 293 K. BaOsF6crystallizes in the space group type R 3¯ with the cell parameters a = 7.3286(10), c = 7.2658(15) Å, V = 337.95(12) Å3, Z = 3 at 100 K. Additionally, we have obtained the compounds Ba(OsF6)2∙3BrF3, Ba(OsF6)2∙HF, Ba(OsF6)2∙6H2O from the respective solvents, and Ba(OsF6)2. | ||
| 461 | |t Crystals | ||
| 463 | |t Vol. 8, iss. 1 |v [11, 10 p.] |d 2018 | ||
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a осмий | |
| 610 | 1 | |a фториды | |
| 610 | 1 | |a трифторид брома | |
| 610 | 1 | |a кристаллические структуры | |
| 610 | 1 | |a osmium | |
| 610 | 1 | |a fluorides | |
| 610 | 1 | |a bromine trifluoride | |
| 610 | 1 | |a crystal structure | |
| 701 | 1 | |a Ivlev |b S. I. |g Sergey Ivanovich | |
| 701 | 1 | |a Karttunen |b A. J. |g Antti | |
| 701 | 1 | |a Buchner |b M. R. |g Magnus | |
| 701 | 1 | |a Ostvald |b R. V. |c Chemical Engineer |c Associate Professor of Tomsk Polytechnic University, Candidate of chemical sciences |f 1980- |g Roman Vyacheslavovich |3 (RuTPU)RU\TPU\pers\31221 |9 15416 | |
| 701 | 1 | |a Kraus |b F. |g Florian | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Инженерная школа ядерных технологий |b Отделение ядерно-топливного цикла |3 (RuTPU)RU\TPU\col\23554 |
| 801 | 2 | |a RU |b 63413507 |c 20180705 |g RCR | |
| 856 | 4 | 0 | |u https://doi.org/10.3390/cryst8010011 |
| 942 | |c CF | ||