Study of the rotational structure of the forbidden ν8 band of the C2H2D2-CIS molecule

Bibliographic Details
Parent link:Russian Physics Journal
Vol. 60, iss. 9.— 2018.— [P. 1644-1649]
Main Author: Konova Yu. V. Yuliya Vladimirovna
Corporate Author: Национальный исследовательский Томский политехнический университет Исследовательская школа физики высокоэнергетических процессов
Summary:Title screen
The spectrum of the cis-ethylene-d2 (C2H2D2-cis) molecule is recorded with a Bruker IFS 120 HR Fourier spectrometer in the region of 600-1200 cm-1 with spectral resolution of 0.0021 cm-1. As a result of analysis of the experimental spectrum, 36 transitions are first assigned, based on which seven upper energy levels of the state (v8 = 1) are determined. The ν8 band is symmetry-forbidden, and its transitions appear in the IR spectrum only due to the strong c-type Coriolis interaction between the states (v8 = 1) and (v7 = 1). The parameters describing the rotational structure of the v8 band are obtained.
Режим доступа: по договору с организацией-держателем ресурса
Language:English
Published: 2018
Subjects:
Online Access:https://doi.org/10.1007/s11182-018-1263-3
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=657964