1,3-Diiodo-5,5-dimethylhydantoin-An efficient reagent for iodination of aromatic compounds

Bibliographic Details
Parent link:	Russian Journal of Organic Chemistry: Scientific Journal.— , 2001- Vol. 43, iss. 9.— 2007.— [P. 1291-1296]
Other Authors:	Chaikovskii V. K. Vitold Kazimirovich, Filimonov V. D. Viktor Dmitrievich, Funk A. A., Skorokhodov V. I., Ogorodnikov V. D.
Summary:	Title screen 1,3-Diiodo-5,5-dimethylhydantoin in organic solvents successfully iodinates alkylbenzenes, aromatic amines, and phenyl ethers. The reactivity of electrophilic iodine is controlled by acidity of the medium. Superelectrophilic iodine generated upon dissolution of 1,3-diiodo-5,5-dimethylhydantoin in sulfuric acid readily reacts with electron-deficient arenes at 0 to 20°C with formation of the corresponding iodo derivatives in good yields. The structure of electrophilic iodine species generated from 1,3-diiodo-5,5- dimethylhydantoin in sulfuric acid is discussed. Режим доступа: по договору с организацией-держателем ресурса
Language:	English
Published:	2007
Subjects:	электронный ресурс труды учёных ТПУ реагенты иодирование ароматические соединения серная кислота
Online Access:	http://dx.doi.org/10.1134/S1070428007090060
Format:	Electronic Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=656658

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