First high resolution analysis of the 3ν2 and 3ν2−ν2 bands of 32S16O2

First high resolution analysis of the 3ν2 and 3ν2−ν2 bands of 32S16O2

Bibliographic Details
Parent link:	Journal of Quantitative Spectroscopy and Radiative Transfer Vol. 202.— 2017.— [P. 1-5]
Corporate Author:	Национальный исследовательский Томский политехнический университет (ТПУ) Физико-технический институт (ФТИ) Кафедра общей физики (ОФ)
Other Authors:	Ulenekov (Ulenikov) O. N. Oleg Nikolaevich, Bekhtereva E. S. Elena Sergeevna, Gromova O. V. Olga Vasilievna, Beryozkin K. B. Kirill Borisovich, Horneman V. M. Veli Matti, Sydow C. Christian, Maul C. Christof, Bauerecker S. Sigurd
Summary:	Title screen The second bending overtone band 3v2 of sulfur dioxide has been studied for the first time with high resolution rotation-vibration spectroscopy. The 1530 transitions involving 728 upper state energy levels with Jmax.= 53 and Kamax.= 15 have been assigned to the 3v2 band. The 746 transitions belonging to the 3v2-v2 "hot" band have been also assigned in the region of 950-1100 cm-1. For the analysis of the assigned transitions, an effective Hamiltonian of an isolated (030) vibrational state (the Watson operator in A-reduction and Ir representation) was used. Set of 9 varied parameters was determined which reproduce the initial experimental data with the drms deviations of 9.0x10-4 cm-1 and 9.8x10-4 cm-1 for the 3v2 and 3v2-v2 bands, which are comparable with the experimental uncertainties. Режим доступа: по договору с организацией-держателем ресурса
Language:	English
Published:	2017
Subjects:	электронный ресурс труды учёных ТПУ S16O2 molecule "hot" bands determination of parameters спектральные параметры двуокись серы спектроскопия
Online Access:	https://doi.org/10.1016/j.jqsrt.2017.07.012
Format:	Electronic Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=655923

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