First high resolution analysis of the 3ν2 and 3ν2−ν2 bands of 32S16O2; Journal of Quantitative Spectroscopy and Radiative Transfer; Vol. 202
| Parent link: | Journal of Quantitative Spectroscopy and Radiative Transfer Vol. 202.— 2017.— [P. 1-5] |
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| Collectivité auteur: | |
| Autres auteurs: | , , , , , , , |
| Résumé: | Title screen The second bending overtone band 3v2 of sulfur dioxide has been studied for the first time with high resolution rotation-vibration spectroscopy. The 1530 transitions involving 728 upper state energy levels with Jmax.= 53 and Kamax.= 15 have been assigned to the 3v2 band. The 746 transitions belonging to the 3v2-v2 "hot" band have been also assigned in the region of 950-1100 cm-1. For the analysis of the assigned transitions, an effective Hamiltonian of an isolated (030) vibrational state (the Watson operator in A-reduction and Ir representation) was used. Set of 9 varied parameters was determined which reproduce the initial experimental data with the drms deviations of 9.0x10-4 cm-1 and 9.8x10-4 cm-1 for the 3v2 and 3v2-v2 bands, which are comparable with the experimental uncertainties. Режим доступа: по договору с организацией-держателем ресурса |
| Langue: | anglais |
| Publié: |
2017
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| Sujets: | |
| Accès en ligne: | https://doi.org/10.1016/j.jqsrt.2017.07.012 |
| Format: | Électronique Chapitre de livre |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=655923 |