First high resolution analysis of the 3ν2 and 3ν2−ν2 bands of 32S16O2; Journal of Quantitative Spectroscopy and Radiative Transfer; Vol. 202
| Parent link: | Journal of Quantitative Spectroscopy and Radiative Transfer Vol. 202.— 2017.— [P. 1-5] |
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| निगमित लेखक: | |
| अन्य लेखक: | , , , , , , , |
| सारांश: | Title screen The second bending overtone band 3v2 of sulfur dioxide has been studied for the first time with high resolution rotation-vibration spectroscopy. The 1530 transitions involving 728 upper state energy levels with Jmax.= 53 and Kamax.= 15 have been assigned to the 3v2 band. The 746 transitions belonging to the 3v2-v2 "hot" band have been also assigned in the region of 950-1100 cm-1. For the analysis of the assigned transitions, an effective Hamiltonian of an isolated (030) vibrational state (the Watson operator in A-reduction and Ir representation) was used. Set of 9 varied parameters was determined which reproduce the initial experimental data with the drms deviations of 9.0x10-4 cm-1 and 9.8x10-4 cm-1 for the 3v2 and 3v2-v2 bands, which are comparable with the experimental uncertainties. Режим доступа: по договору с организацией-держателем ресурса |
| भाषा: | अंग्रेज़ी |
| प्रकाशित: |
2017
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| विषय: | |
| ऑनलाइन पहुंच: | https://doi.org/10.1016/j.jqsrt.2017.07.012 |
| स्वरूप: | इलेक्ट्रोनिक पुस्तक अध्याय |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=655923 |
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| 200 | 1 | |a First high resolution analysis of the 3ν2 and 3ν2−ν2 bands of 32S16O2 |f O. N. Ulenikov [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: p. 349-350 (66 tit.)] | ||
| 330 | |a The second bending overtone band 3v2 of sulfur dioxide has been studied for the first time with high resolution rotation-vibration spectroscopy. The 1530 transitions involving 728 upper state energy levels with Jmax.= 53 and Kamax.= 15 have been assigned to the 3v2 band. The 746 transitions belonging to the 3v2-v2 "hot" band have been also assigned in the region of 950-1100 cm-1. For the analysis of the assigned transitions, an effective Hamiltonian of an isolated (030) vibrational state (the Watson operator in A-reduction and Ir representation) was used. Set of 9 varied parameters was determined which reproduce the initial experimental data with the drms deviations of 9.0x10-4 cm-1 and 9.8x10-4 cm-1 for the 3v2 and 3v2-v2 bands, which are comparable with the experimental uncertainties. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Journal of Quantitative Spectroscopy and Radiative Transfer | ||
| 463 | |t Vol. 202 |v [P. 1-5] |d 2017 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a S16O2 molecule | |
| 610 | 1 | |a "hot" bands | |
| 610 | 1 | |a determination of parameters | |
| 610 | 1 | |a спектральные параметры | |
| 610 | 1 | |a двуокись серы | |
| 610 | 1 | |a спектроскопия | |
| 701 | 1 | |a Ulenekov (Ulenikov) |b O. N. |c physicist |c Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences |f 1949- |g Oleg Nikolaevich |3 (RuTPU)RU\TPU\pers\34331 |9 17837 | |
| 701 | 1 | |a Bekhtereva |b E. S. |c physicist |c Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences |f 1974- |g Elena Sergeevna |3 (RuTPU)RU\TPU\pers\34450 |9 17851 | |
| 701 | 1 | |a Gromova |b O. V. |c physicist |c Professor of Tomsk Polytechnic University, Candidate of physical and mathematical sciences |f 1982- |g Olga Vasilievna |3 (RuTPU)RU\TPU\pers\34333 |9 17839 | |
| 701 | 1 | |a Beryozkin |b K. B. |c physicist |c technician Tomsk Polytechnic University |f 1987- |g Kirill Borisovich |3 (RuTPU)RU\TPU\pers\34702 | |
| 701 | 1 | |a Horneman |b V. M. |g Veli Matti | |
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