High resolution Fourier transform infrared spectroscopy of the ground state, ν3,2ν3 and ν4 levels of 13CHF3

書目詳細資料
Parent link:Journal of Molecular Spectroscopy
Vol. 337.— 2017.— [P. 96-104]
其他作者: Bolotova I. B. Irina Batorovna, Ulenekov (Ulenikov) O. N. Oleg Nikolaevich, Bekhtereva E. S. Elena Sergeevna, Albert S. Sieghard, Chen Ziqiu, Hollenstein H. A. Hans, Zindel D. Daniel, Quack M. Martin
總結:Title screen
We report high resolution ([delta]v<=0.001cm-1) Fourier Transform Infrared (FTIR) spectra of the trifluoromethane (fluoroform) isotopomer 13CHF3 including results from synchrotron based spectroscopy at the Swiss light source (SLS). The analysis is extended to the pure rotational spectra in the Terahertz (far-infrared) range (15-100 cm−1, [delta]vWHM=0.0006cm-1), the v3fundamental (v0=695.292cm-1), the associated “hot” band 2v3-v3 providing information on the level 2v3 (v0=1389.807cm-1) and the v4 fundamental (v0=1369.013cm-1) coupled to 2ν3. The results are discussed in relation to the 13C isotope effect on the vibrational quantum dynamics as derived by theory and in relation to fluoroform as a greenhouse gas.
Режим доступа: по договору с организацией-держателем ресурса
語言:英语
出版: 2017
主題:
在線閱讀:https://doi.org/10.1016/j.jms.2017.05.003
格式: 電子 Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=655921