High resolution Fourier transform infrared spectroscopy of the ground state, ν3,2ν3 and ν4 levels of 13CHF3

High resolution Fourier transform infrared spectroscopy of the ground state, ν3,2ν3 and ν4 levels of 13CHF3

书目详细资料
Parent link:	Journal of Molecular Spectroscopy Vol. 337.— 2017.— [P. 96-104]
其他作者:	Bolotova I. B. Irina Batorovna, Ulenekov (Ulenikov) O. N. Oleg Nikolaevich, Bekhtereva E. S. Elena Sergeevna, Albert S. Sieghard, Chen Ziqiu, Hollenstein H. A. Hans, Zindel D. Daniel, Quack M. Martin
总结:	Title screen We report high resolution ([delta]v<=0.001cm-1) Fourier Transform Infrared (FTIR) spectra of the trifluoromethane (fluoroform) isotopomer 13CHF3 including results from synchrotron based spectroscopy at the Swiss light source (SLS). The analysis is extended to the pure rotational spectra in the Terahertz (far-infrared) range (15-100 cm−1, [delta]vWHM=0.0006cm-1), the v3fundamental (v0=695.292cm-1), the associated “hot” band 2v3-v3 providing information on the level 2v3 (v0=1389.807cm-1) and the v4 fundamental (v0=1369.013cm-1) coupled to 2ν3. The results are discussed in relation to the 13C isotope effect on the vibrational quantum dynamics as derived by theory and in relation to fluoroform as a greenhouse gas. Режим доступа: по договору с организацией-держателем ресурса
语言:	英语
出版:	2017
主题:	электронный ресурс труды учёных ТПУ fluoroform high resolution infrared spectroscopy FTIR THz инфракрасная спектроскопия ИК-Фурье спектроскопия вращательные спектры
在线阅读:	https://doi.org/10.1016/j.jms.2017.05.003
格式:	电子本书章节
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=655921

因特网

https://doi.org/10.1016/j.jms.2017.05.003