High resolution Fourier transform infrared spectroscopy of the ground state, ν3,2ν3 and ν4 levels of 13CHF3
| Parent link: | Journal of Molecular Spectroscopy Vol. 337.— 2017.— [P. 96-104] |
|---|---|
| Corporate Author: | |
| Other Authors: | , , , , , , , |
| Summary: | Title screen We report high resolution ([delta]v<=0.001cm-1) Fourier Transform Infrared (FTIR) spectra of the trifluoromethane (fluoroform) isotopomer 13CHF3 including results from synchrotron based spectroscopy at the Swiss light source (SLS). The analysis is extended to the pure rotational spectra in the Terahertz (far-infrared) range (15-100 cm−1, [delta]vWHM=0.0006cm-1), the v3fundamental (v0=695.292cm-1), the associated “hot” band 2v3-v3 providing information on the level 2v3 (v0=1389.807cm-1) and the v4 fundamental (v0=1369.013cm-1) coupled to 2ν3. The results are discussed in relation to the 13C isotope effect on the vibrational quantum dynamics as derived by theory and in relation to fluoroform as a greenhouse gas. Режим доступа: по договору с организацией-держателем ресурса |
| Published: |
2017
|
| Subjects: | |
| Online Access: | https://doi.org/10.1016/j.jms.2017.05.003 |
| Format: | Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=655921 |
MARC
| LEADER | 00000naa0a2200000 4500 | ||
|---|---|---|---|
| 001 | 655921 | ||
| 005 | 20250331132034.0 | ||
| 035 | |a (RuTPU)RU\TPU\network\22261 | ||
| 090 | |a 655921 | ||
| 100 | |a 20171012d2017 k||y0rusy50 ba | ||
| 101 | 0 | |a eng | |
| 135 | |a drcn ---uucaa | ||
| 181 | 0 | |a i | |
| 182 | 0 | |a b | |
| 200 | 1 | |a High resolution Fourier transform infrared spectroscopy of the ground state, ν3,2ν3 and ν4 levels of 13CHF3 |f I. B. Bolotova [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: p. 104 (53 tit.)] | ||
| 330 | |a We report high resolution ([delta]v<=0.001cm-1) Fourier Transform Infrared (FTIR) spectra of the trifluoromethane (fluoroform) isotopomer 13CHF3 including results from synchrotron based spectroscopy at the Swiss light source (SLS). The analysis is extended to the pure rotational spectra in the Terahertz (far-infrared) range (15-100 cm−1, [delta]vWHM=0.0006cm-1), the v3fundamental (v0=695.292cm-1), the associated “hot” band 2v3-v3 providing information on the level 2v3 (v0=1389.807cm-1) and the v4 fundamental (v0=1369.013cm-1) coupled to 2ν3. The results are discussed in relation to the 13C isotope effect on the vibrational quantum dynamics as derived by theory and in relation to fluoroform as a greenhouse gas. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Journal of Molecular Spectroscopy | ||
| 463 | |t Vol. 337 |v [P. 96-104] |d 2017 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a fluoroform | |
| 610 | 1 | |a high resolution infrared spectroscopy | |
| 610 | 1 | |a FTIR | |
| 610 | 1 | |a THz | |
| 610 | 1 | |a инфракрасная спектроскопия | |
| 610 | 1 | |a ИК-Фурье спектроскопия | |
| 610 | 1 | |a вращательные спектры | |
| 701 | 1 | |a Bolotova |b I. B. |c physicist |c Technician of Tomsk Polytechnic University |f 1989- |g Irina Batorovna |3 (RuTPU)RU\TPU\pers\34081 | |
| 701 | 1 | |a Ulenekov (Ulenikov) |b O. N. |c physicist |c Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences |f 1949- |g Oleg Nikolaevich |3 (RuTPU)RU\TPU\pers\34331 |9 17837 | |
| 701 | 1 | |a Bekhtereva |b E. S. |c physicist |c Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences |f 1974- |g Elena Sergeevna |3 (RuTPU)RU\TPU\pers\34450 |9 17851 | |
| 701 | 1 | |a Albert |b S. |g Sieghard | |
| 701 | 0 | |a Chen Ziqiu | |
| 701 | 1 | |a Hollenstein |b H. A. |g Hans | |
| 701 | 1 | |a Zindel |b D. |g Daniel | |
| 701 | 1 | |a Quack |b M. |g Martin | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет (ТПУ) |b Физико-технический институт (ФТИ) |b Кафедра общей физики (ОФ) |3 (RuTPU)RU\TPU\col\18734 |
| 801 | 2 | |a RU |b 63413507 |c 20171012 |g RCR | |
| 856 | 4 | |u https://doi.org/10.1016/j.jms.2017.05.003 | |
| 942 | |c CF | ||