A new transformation of aminopyridines upon diazotization in acetonitrile with the formation of N-pyridinylacetamides

A new transformation of aminopyridines upon diazotization in acetonitrile with the formation of N-pyridinylacetamides

Bibliographic Details
Parent link:Russian Chemical Bulletin: Scientific Journal
Vol. 65, iss. 9.— 2016.— [P. 2312–2314]
Corporate Author: Национальный исследовательский Томский политехнический университет (ТПУ) Институт физики высоких технологий (ИФВТ) Кафедра биотехнологии и органической химии (БИОХ)
Other Authors: Chudinov A. A. Aleksey Andreevich, Dovbnya R. S. Rada Sergeevna, Krasnokutskaya E. A . Elena Aleksandrovna, Ogorodnikov V. D. Vladimir Danilovich, Filimonova I. L. Irina Leonidovna
Summary:Title screen
Diazotization of aminopyridines upon treatment with NaNO2 and H3PO4 in acetonitrile led to the formation of N-pyridinylacetamides. This reaction constitutes a convenient and general preparative method for the synthesis of 2-, 3-, and 4-N-pyridinylacetamides under mild conditions in good yields. The in situ oxidation of the thus obtained N-pyridinylacetamides with hydrogen peroxide gave good yields of pyridinylacetamide N-oxides.
Режим доступа: по договору с организацией-держателем ресурса
Published: 2016
Subjects:
электронный ресурс
труды учёных ТПУ
aminopyridines
diazotization
N-pyridinylacetamides
oxidation
аминопиридины
диазотирование
окисление
Online Access:https://doi.org/10.1007/s11172-016-1583-9
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=655631

Internet

https://doi.org/10.1007/s11172-016-1583-9

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