High time resolution spectroscopy studies of the explosive decomposition of silver azide
| Parent link: | Russian Physics Journal.— , 1965- Vol. 39, iss. 11.— 1996.— [P. 1135-1145] |
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| Altri autori: | , , , , |
| Riassunto: | Title screen We have analyzed the existing assumptions about the mechanism of the explosive decomposition of the heavy metal azides. We present here a study of the kinetics of the explosive decomposition of silver azide, initiated by a laser pulse. New effects are identified and studied, including a pre-explosion conductivity and luminescence. On the basis of our results, we conclude that the reaction proceeds by a chain reaction mechanism. In terms of band theory, we propose a model of the primary chain step of the reaction as the creation of a quasilocalized state deep in the valence band with two holes localized at a defect (N30), with impact ionization occurring as they “float up”. Режим доступа: по договору с организацией-держателем ресурса |
| Lingua: | inglese |
| Pubblicazione: |
1996
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| Soggetti: | |
| Accesso online: | http://dx.doi.org/10.1007/BF02436156 |
| Natura: | Elettronico Capitolo di libro |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=654774 |