Transformations of Diphenyl Sulfide and Diphenylamine on Aluminum Chloride

Transformations of Diphenyl Sulfide and Diphenylamine on Aluminum Chloride

Bibliographic Details
Parent link:	Petroleum Chemistry.— , 2006- Vol. 57, iss. 3.— 2017.— [P. 272–277]
Corporate Author:	Национальный исследовательский Томский политехнический университет (ТПУ) Юргинский технологический институт (филиал) (ЮТИ) Кафедра сварочного производства (КСП)
Other Authors:	Nekhoroshev V. P. Viktor Petrovich, Gubayddulin R. R. Rustem Rinatovich, Yarkova A. G. Anna Gennadjevna, Nekhorosheva A. V. Aleksandra Viktorovna, Nifantjev I. E. Iljya Eduardovich, Voronkov E. O. Evgeny Olegovich, Poleshchuk O. Kh. Oleg Khemovich, Tarasova O. I. Oksana Igorevna
Summary:	Title screen Thianthrene has been synthesized by reacting diphenyl sulfide with AlCl3 in heptane at 98°C for 8 h at a diphenyl sulfide : AlCl3 molar ratio of 2 : 1; the thianthrene yield is 58%. The reaction mechanism proposed previously has been confirmed by quantum-chemical calculations; the reaction is characterized by a low negative value of Gibbs free energy, a low heat of reaction, and a high activation energy of the first step. Diphenyl ether and diphenylamine do not enter the test reaction because of low nucleophilicity of the heteroatoms; diphenylamine dimerizes under the reaction conditions to form N,N'-diphenylbenzidine. Режим доступа: по договору с организацией-держателем ресурса
Published:	2017
Subjects:	электронный ресурс труды учёных ТПУ diphenylamine thianthrene дифениламин дифенил хлорид алюминия
Online Access:	http://dx.doi.org/10.1134/S0965544117020207
Format:	Electronic Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=654604

Internet

http://dx.doi.org/10.1134/S0965544117020207