9-Alkenylcarbazoles

Detaylı Bibliyografya
Parent link:Chemistry of Heterocyclic Compounds
Vol. 16, iss. 3.— 1980.— [P. 252-255]
Yazar: Filimonov V. D. Viktor Dmitrievich
Diğer Yazarlar: Gorbachev S. G., Sirotkina E. E.
Özet:Title screen
A number of cis-9-propenylcarbazoles were synthesized in good yields by isomerization of 9-allylcarbazoles by the action of tert-BuOK in dimethyl sulfoxide. It was established that cis-9-propenylcarbazole is less thermodynamically stable than its trans isomer. It was shown by13C NMR, UV, and IR spectroscopy that the effect of p-π conjugation in cis-9-propenylcarbazole decreases as compared with the trans isomer as a result of the noncoplanarity of the C=C bond and the carbazole ring.
Режим доступа: по договору с организацией-держателем ресурса
Dil:İngilizce
Baskı/Yayın Bilgisi: 1980
Konular:
Online Erişim:http://dx.doi.org/10.1007/BF02401721
Materyal Türü: Elektronik Kitap Bölümü
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=654467