10-Alkenylphenothiazines; 2; Synthesis and mechanism of acidic hydrolysis of cis- and trans-10-2-phenylvinyl)phenothiazines; Chemistry of Heterocyclic Compounds; Vol. 22, iss. 10
| Parent link: | Chemistry of Heterocyclic Compounds Vol. 22, iss. 10.— 1986.— [P. 1152-1157] |
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| Diğer Yazarlar: | , , , , |
| Özet: | Title screen The addition of phenothiazine to phenylacetylene in super-base media proceeds regio- and stereoselectively and leads to the predominant formation of cis-10-(2-phenylvinyl)phenothiazine, which is completely converted to its trans-isomer at 200‡C. Kinetic analysis of the acidic hydrolysis of the cis- and transisomers has allowed us to assign to it an ASE2 reaction mechanism, similar to the mechanism of hydrolysis of vinyl alkyl ethers. Режим доступа: по договору с организацией-держателем ресурса |
| Dil: | İngilizce |
| Baskı/Yayın Bilgisi: |
1986
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| Konular: | |
| Online Erişim: | http://dx.doi.org/10.1007/BF00473499 |
| Materyal Türü: | Elektronik Kitap Bölümü |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=654435 |
| Özet: | Title screen The addition of phenothiazine to phenylacetylene in super-base media proceeds regio- and stereoselectively and leads to the predominant formation of cis-10-(2-phenylvinyl)phenothiazine, which is completely converted to its trans-isomer at 200‡C. Kinetic analysis of the acidic hydrolysis of the cis- and transisomers has allowed us to assign to it an ASE2 reaction mechanism, similar to the mechanism of hydrolysis of vinyl alkyl ethers. Режим доступа: по договору с организацией-держателем ресурса |
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| DOI: | 10.1007/BF00473499 |