10-Alkenylphenothiazines; 2; Synthesis and mechanism of acidic hydrolysis of cis- and trans-10-2-phenylvinyl)phenothiazines; Chemistry of Heterocyclic Compounds; Vol. 22, iss. 10

Bibliographic Details
Parent link:Chemistry of Heterocyclic Compounds
Vol. 22, iss. 10.— 1986.— [P. 1152-1157]
Other Authors: Anfinogenov V. A., Napilkova O. A., Sirotkina E. E., Filimonov V. D. Viktor Dmitrievich, Khlebnikov A. I. Andrey Ivanovich
Summary:Title screen
The addition of phenothiazine to phenylacetylene in super-base media proceeds regio- and stereoselectively and leads to the predominant formation of cis-10-(2-phenylvinyl)phenothiazine, which is completely converted to its trans-isomer at 200‡C. Kinetic analysis of the acidic hydrolysis of the cis- and transisomers has allowed us to assign to it an ASE2 reaction mechanism, similar to the mechanism of hydrolysis of vinyl alkyl ethers.
Режим доступа: по договору с организацией-держателем ресурса
Language:English
Published: 1986
Subjects:
Online Access:http://dx.doi.org/10.1007/BF00473499
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=654435