Coal char oxidation kinetics in air medium

Bibliographic Details
Parent link:AIP Conference Proceedings
Vol. 1800 : Youth, Science, Solutions: Ideas and Prospects (YSSIP-2016).— 2017.— [020014, 4 p.]
Corporate Author: Национальный исследовательский Томский политехнический университет (ТПУ) Энергетический институт (ЭНИН) Кафедра атомных и тепловых электростанций (АТЭС)
Other Authors: Slusarskiy (Slyusarsky) K. V. Konstantin Vitalievich, Yankovsky S. A. Stanislav Aleksandrovich, Korotkikh A. G. Aleksandr Gennadievich, Sorokin I. V. Ivan Viktorovich
Summary:Title screen
Research on oxidation in air medium process of three different coal chars with various carbon content was presented. The anthracite, T-grade bituminous coal and 2B-grade lignite char powders with particle size less than 80?µm were studied. The coal char oxidation was studied by isothermal method using coupled TG-DSC analyzer Netzsch STA 449 Jupiter F3 in the temperature range 1000-1200 °C. Experiments were carried out at ambient pressure. Volumetric flow rate of oxidation medium into analyzer chamber was 250?ml/min and consisted of oxygen and argon with volumetric ratio 24:1. Based on experimental data, the average rate of carbon oxidation reaction values were defined at each temperature. Kinetic constants (frequency factor and activation energy) of reaction were defined as well via 1st order Arrhenius equation. Activation energy values are in good agreement with the data presented in the literature. Activation energy values for anthracite char are 1.6-1.7 times higher than those for bituminous coal and lignite chars, respectively.
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Published: 2017
Subjects:
Online Access:http://dx.doi.org/10.1063/1.4973030
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=654405