First study of the ro-vibrational structure of the g-symmetry vibrational states of C2D4 from the analysis of hot bands: The v7+v10-v10 and v10+v12-v10 bands; Journal of Quantitative Spectroscopy and Radiative Transfer; Vol. 187
| Parent link: | Journal of Quantitative Spectroscopy and Radiative Transfer Vol. 187.— 2017.— [P. 178–189] |
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| Corporate Author: | |
| Other Authors: | , , , , , , |
| Summary: | Title screen The two strongest absorption "hot" bands of C2D4, ν7+ν10−ν10 and ν10+ν12−ν10 were analyzed for the first time on the basis of high resolution infrared spectra recorded with a Bruker high resolution Fourier transform spectrometer. About 740 and 550 transitions (233 and 174 upper state ro-vibrational energy values) with Jmax.=25, Ka,max =18 and Jmax.=20, Ka,max =10 for the bands ν7+ν10−ν10 and ν10+ν12−ν10 were assigned. The obtained upper ro-vibrational energies were used then in the weighted fit of parameters of the effective Hamiltonian which takes into account resonance interactions between the vibrational states (v7=v10=1) and (v10=v12=1), on the one hand, and eight other closely located vibrational states, on the other hand. A set of 46 varied parameters was obtained from the fit, which reproduces the initial experimental data with the rms deviation of 2.5 x 10[-4] cm[-1] and which is close to experimental uncertainties. Режим доступа: по договору с организацией-держателем ресурса |
| Language: | English |
| Published: |
2017
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| Subjects: | |
| Online Access: | http://dx.doi.org/10.1016/j.jqsrt.2016.09.014 |
| Format: | Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=653234 |
MARC
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| 200 | 1 | |a First study of the ro-vibrational structure of the g-symmetry vibrational states of C2D4 from the analysis of hot bands: The v7+v10-v10 and v10+v12-v10 bands |f O. N. Ulenikov [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: p. 188-189 (67 tit.] | ||
| 330 | |a The two strongest absorption "hot" bands of C2D4, ν7+ν10−ν10 and ν10+ν12−ν10 were analyzed for the first time on the basis of high resolution infrared spectra recorded with a Bruker high resolution Fourier transform spectrometer. About 740 and 550 transitions (233 and 174 upper state ro-vibrational energy values) with Jmax.=25, Ka,max =18 and Jmax.=20, Ka,max =10 for the bands ν7+ν10−ν10 and ν10+ν12−ν10 were assigned. The obtained upper ro-vibrational energies were used then in the weighted fit of parameters of the effective Hamiltonian which takes into account resonance interactions between the vibrational states (v7=v10=1) and (v10=v12=1), on the one hand, and eight other closely located vibrational states, on the other hand. A set of 46 varied parameters was obtained from the fit, which reproduces the initial experimental data with the rms deviation of 2.5 x 10[-4] cm[-1] and which is close to experimental uncertainties. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Journal of Quantitative Spectroscopy and Radiative Transfer | ||
| 463 | |t Vol. 187 |v [P. 178–189] |d 2017 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a C2D4 | |
| 610 | 1 | |a high-resolution spectra | |
| 610 | 1 | |a spectroscopic parameters | |
| 610 | 1 | |a hot band | |
| 610 | 1 | |a спектры высокого разрешения | |
| 610 | 1 | |a спектроскопические параметры | |
| 610 | 1 | |a горячие полосы | |
| 701 | 1 | |a Ulenekov (Ulenikov) |b O. N. |c physicist |c Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences |f 1949- |g Oleg Nikolaevich |3 (RuTPU)RU\TPU\pers\34331 |9 17837 | |
| 701 | 1 | |a Gromova |b O. V. |c physicist |c Professor of Tomsk Polytechnic University, Candidate of physical and mathematical sciences |f 1982- |g Olga Vasilievna |3 (RuTPU)RU\TPU\pers\34333 |9 17839 | |
| 701 | 1 | |a Bekhtereva |b E. S. |c physicist |c Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences |f 1974- |g Elena Sergeevna |3 (RuTPU)RU\TPU\pers\34450 |9 17851 | |
| 701 | 1 | |a Fomchenko |b A. L. |c physicist |c research engineer at Tomsk Polytechnic University, candidate of physical and mathematical Sciences |f 1987- |g Anna Leonidovna |3 (RuTPU)RU\TPU\pers\34089 |9 17645 | |
| 701 | 1 | |a Sydow |b C. | |
| 701 | 1 | |a Maul |b C. |g Christof | |
| 701 | 1 | |a Bauerecker |b S. |g Sigurd | |
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