Cr[2]O[3]/Al-Al[2]O[3] composite catalysts for hydrocarbons dehydrogenation prepared from aluminum nanopowder
| Parent link: | AIP Conference Proceedings Vol. 1772 : Prospects of Fundamental Sciences Development (PFSD-2016).— 2016.— [030018, 8 p.] |
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| مؤلفون آخرون: | , , , , |
| الملخص: | Title screen Aluminum nanopowder (10-150 nm) was treated hydrothermally in mild conditions (60-95 °C, at atmospheric pressure), and an aluminum-alumina composite with high porosity and specific surface area was obtained. Cr[2]O[3]/Al-Al[2]O[3] catalysts were prepared using the aluminum-alumina composite by impregnation techniques and tested in dehydrogenation of C[4]-hydrocarbons. It was shown that aluminum-alumina composites had high chemical and phase purity, specific surface area of 150-350 m{2}/g and the average pore size of 8-13 nm, that is favorable for application as support for catalysts. Cr[2]O[3]/Al-Al[2]O[3] catalysts had high activity and selectivity in dehydrogenation of n- and i-butane (conversion of 44-80 mol.% and selectivity >85% at temperatures of 540-610 °C), that is comparable ones for commercial catalysts for CATOFIN, STAR processes. Режим доступа: по договору с организацией-держателем ресурса |
| اللغة: | الإنجليزية |
| منشور في: |
2016
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| سلاسل: | Materials structure and properties under modification |
| الموضوعات: | |
| الوصول للمادة أونلاين: | http://dx.doi.org/10.1063/1.4964556 http://earchive.tpu.ru/handle/11683/35000 |
| التنسيق: | الكتروني فصل الكتاب |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=652115 |