The processes in film-forming solution based on tetraethoxysilane, phosphoric acid and calcium chloride

Bibliographic Details
Parent link:AIP Conference Proceedings
Vol. 1772 : Prospects of Fundamental Sciences Development (PFSD-2016).— 2016.— [020006, 7 p.]
Corporate Authors: Национальный исследовательский Томский политехнический университет (ТПУ) Институт физики высоких технологий (ИФВТ) Кафедра технологии силикатов и наноматериалов (ТСН), Национальный исследовательский Томский политехнический университет (ТПУ) Юргинский технологический институт (филиал) (ЮТИ) Кафедра безопасности жизнедеятельности, экологии и физического воспитания (БЖДЭФВ)
Other Authors: Petrovskaya T. S. Tatyana Semyonovna, Kuznetsova S. Svetlana, Borilo L. Liudmila, Kozik V. V. Vladimir Vasilievich
Summary:Title screen
Physical and chemical patterns film-forming ethanol solution based on tetraethoxysilane, orthophosphoric acid and calcium chloride have been determined. Methods of photon correlation spectrometry and electrophoresis showed that colloidal particles with size up to 25 nm are formed in the film-forming solutions. Their stability is maintained during one day, and then CaHPO[4] precipitates from the film-forming solutions. Methods of X-ray analysis, scanning electron microscopy and IR spectroscopy have shown that the dried coating solution after precipitation of CaHPO4 consists of CaClH[2]PO[4]·H[2]O and SiO[2]. The formation of these substances is due to the hydrolysis of tetraethoxysilane and interaction calciumchloride with orthophosphoric acid.
Режим доступа: по договору с организацией-держателем ресурса
Published: 2016
Series:Synthesis and physicochemical characteristics of materials
Subjects:
Online Access:http://dx.doi.org/10.1063/1.4964528
http://earchive.tpu.ru/handle/11683/35020
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=652076