Preparation of ordered silver angular nanoparticles array in block copolymer film for surface-enhanced Raman spectroscopy

Bibliographic Details
Parent link:Journal of Nanoparticle Research
Vol. 18, iss. 10.— 2016.— [289, 8 p.]
Corporate Author: Национальный исследовательский Томский политехнический университет Институт природных ресурсов Кафедра технологии органических веществ и полимерных материалов
Other Authors: Svanda J. Jan, Gromov M. V. Maksim Valerjevich, Kalacheva E. S. Evgeniya Sergeevna, Postnikov P. S. Pavel Sergeevich, Svorcik V., Lyutakov O. Oleksy
Summary:Title screen
We report a single-step method of preparation of ordered silver nanoparticles array through template-assisted nanoparticles synthesis in the semidried block copolymer film. Ordered nanoparticles were prepared on different substrates by the proper choice of solvents combination and preparation procedure. In particular, block copolymer and silver nitrate were dissolved in the mix of tetrahydrofuran, toluene, and n-methylpyrolidone. During short spin-coating procedure ordering of block copolymer, evaporation of toluene and preferential silver redistribution into poly(4-vinylpyridine) block occurred. Rapid heating of semidry film initiated silver reduction, removing of residual solvent and creation of ordered silver array. After polymer removing silver nanoparticles array was tested as a suitable candidate for subdiffraction plasmonic application–surface-enhanced Raman scattering. Enhancement factor was calculated and compared with the literature data.
Режим доступа: по договору с организацией-держателем ресурса
Language:English
Published: 2016
Subjects:
Online Access:http://dx.doi.org/10.1007/s11051-016-3599-3
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=651266