Thermal stability and hydrogenation behavior of Zr-1Nb alloy with TiNx and Ti/TiNx coatings

Bibliographic Details
Parent link:Journal of Physics: Conference Series
Vol. 741 : Optoelectronics, Photonics, Engineering and Nanostructures (Saint Petersburg OPEN 2016).— 2016.— [012192, 6 p.]
Main Author: Kashkarov E. B. Egor Borisovich
Corporate Author: Национальный исследовательский Томский политехнический университет (ТПУ) Физико-технический институт (ФТИ) Кафедра общей физики (ОФ)
Other Authors: Vilkhivskaya O. V. Olga Vladimirovna, Zakharchenko S. A. Svetlana Aleksandrovna
Summary:Title screen
Titanium nitride coatings were deposited by reactive dc magnetron sputtering (dcMS) to protect Zr-1Nb alloys from hydrogen embrittlement. Dense titanium (Ti) interlayer was prepared between TiNx protection film and a Zr substrate to improve thermal stability and adhesion between the TiNx and the substrate at high temperatures. Hydrogen absorption of Zr- 1Nb with TiNx and Ti/TiNx at 623 K was reduced in comparison with uncoated Zr-1Nb. No peeling or cracks of Ti/TiNx coatings is observed after thermal cycling up to 1073 K. The high temperature (1073 K) hydrogenation behaviour differs from the hydrogenation at lower temperature by increasing the amount of dissolved hydrogen in the phase of zirconium. The higher rate of hydrogen absorption by Zr-1Nb with TiNx was observed due to the coating delamination as a result of differences in thermal expansion coefficients, while Ti/TiNx demonstrates the lower hydrogen absorption at 1073 K and good adhesion strength.
Language:English
Published: 2016
Subjects:
Online Access:http://earchive.tpu.ru/handle/11683/36140
http://dx.doi.org/10.1088/1742-6596/741/1/012192
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=650702