2-Iodoxybenzoic acid organosulfonates: preparation, X-ray structure and reactivity of new, powerful hypervalent iodine(V) oxidants

Bibliographic Details
Parent link:Chemical Communications.— , 1989-
Vol. 49, iss. 96.— 2013.— [P. 11269-11271]
Corporate Author: Национальный исследовательский Томский политехнический университет Институт природных ресурсов Кафедра технологии органических веществ и полимерных материалов
Other Authors: Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Svitich D. Yu. Dmitry Yurjevich, Yoshimura A. Akira, Nemykin V. N., Zhdankin V. V. Viktor Vladimirovich
Summary:Title screen
New powerful hypervalent iodine(V) oxidants, tosylate and mesylate derivatives of 2-iodoxybenzoic acid (IBX), were prepared by the reaction of IBX with the corresponding sulfonic acids. Single crystal X-ray crystallography of the diacetate derivative of IBX-tosylate revealed an unusual heptacoordinated iodine geometry without any significant intermolecular secondary interactions.
Published: 2013
Subjects:
Online Access:http://dx.doi.org/10.1039/C3CC47090C
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=650196