Preparation and X-ray Structures of 3-[Bis(trifluoroacetoxy)iodo]benzoic Acid and 3-[Hydroxy(tosyloxy)iodo]benzoic Acid: New Recyclable Hypervalent Iodine Reagents

Bibliographic Details
Parent link:	The Journal of Organic Chemistry.— , 1936- Vol. 73, iss. 1.— 2008.— [P. 292-297]
Other Authors:	Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Funk Т. V., Chi Ki-Whan, Cha Eun-Hye, Kim Ghyung Hwa, Kirschning А., Zhdankin V. V. Viktor Vladimirovich
Summary:	Title screen Preparation, structural characterization, and reactivity of 3-[bis(trifluoroacetoxy)iodo]benzoic acid and 3-[hydroxy(tosyloxy)iodo]benzoic acid, new recyclable iodine(III) reagents derived from 3-iodosylbenzoic acid, are described. The reduced form of these reagents, 3-iodobenzoic acid, can be easily recovered from the reaction mixtures using ion-exchange resin or basic aqueous workup followed by acidification with HCl. Режим доступа: по договору с организацией-держателем ресурса
Language:	English
Published:	2008
Subjects:	электронный ресурс труды учёных ТПУ иод соединения гипервалентные соединения кристаллические стуктуры бензойная кислота синтез
Online Access:	http://dx.doi.org/10.1021/jo702112s
Format:	Electronic Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=650180

Internet

http://dx.doi.org/10.1021/jo702112s