Preparation and X-ray Structural Study of 1-Arylbenziodoxolones; The Journal of Organic Chemistry; Vol. 78, iss. 8
| Parent link: | The Journal of Organic Chemistry.— , 1936- Vol. 78, iss. 8.— 2013.— [P. 3767-3773] |
|---|---|
| Ente Autore: | Национальный исследовательский Томский политехнический университет Институт природных ресурсов Кафедра технологии органических веществ и полимерных материалов |
| Altri autori: | Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Yusubova R. Ya. Roza Yavidovna, Nemykin V. N., Zhdankin V. V. Viktor Vladimirovich |
| Riassunto: | Title screen Various 1-arylbenziodoxolones can be conveniently prepared from 2-iodobenzoic acid and arenes by a one-pot procedure using Oxone (2KHSO5·KHSO4·K2SO4) as an inexpensive and environmentally safe oxidant. This procedure is also applicable for the synthesis of the 7-methylbenziodoxolone ring system using 2-iodo-3-methylbenzoic acid as starting compound. Structures of four 1-arylbenziodoxolone derivatives were established by single-crystal X-ray diffraction analysis. An enhanced reactivity of 1-aryl-7-methylbenziodoxolones toward nucleophiles compared to unsubstituted 1-arylbenziodoxolones has been found. Режим доступа: по договору с организацией-держателем ресурса |
| Lingua: | inglese |
| Pubblicazione: |
2013
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| Soggetti: | |
| Accesso online: | http://dx.doi.org/10.1021/jo400212u |
| Natura: | Elettronico Capitolo di libro |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=650158 |
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