Preparation and X-ray Structural Study of 1-Arylbenziodoxolones

Preparation and X-ray Structural Study of 1-Arylbenziodoxolones

Bibliographic Details
Parent link:	The Journal of Organic Chemistry.— , 1936- Vol. 78, iss. 8.— 2013.— [P. 3767-3773]
Corporate Author:	Национальный исследовательский Томский политехнический университет Институт природных ресурсов Кафедра технологии органических веществ и полимерных материалов
Other Authors:	Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Yusubova R. Ya. Roza Yavidovna, Nemykin V. N., Zhdankin V. V. Viktor Vladimirovich
Summary:	Title screen Various 1-arylbenziodoxolones can be conveniently prepared from 2-iodobenzoic acid and arenes by a one-pot procedure using Oxone (2KHSO5·KHSO4·K2SO4) as an inexpensive and environmentally safe oxidant. This procedure is also applicable for the synthesis of the 7-methylbenziodoxolone ring system using 2-iodo-3-methylbenzoic acid as starting compound. Structures of four 1-arylbenziodoxolone derivatives were established by single-crystal X-ray diffraction analysis. An enhanced reactivity of 1-aryl-7-methylbenziodoxolones toward nucleophiles compared to unsubstituted 1-arylbenziodoxolones has been found. Режим доступа: по договору с организацией-держателем ресурса
Published:	2013
Subjects:	электронный ресурс труды учёных ТПУ иод реакции бензойные кислоты углеводороды калий пероксисульфаты бензиодоксолоны синтез органические структуры гипервалентные соединения
Online Access:	http://dx.doi.org/10.1021/jo400212u
Format:	Electronic Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=650158

Internet

http://dx.doi.org/10.1021/jo400212u