Binuclear iron(III) octakis(perfluorophenyl)tetraazaporphyrin μ-oxodimer: a highly efficient catalyst for biomimetic oxygenation reactions

Binuclear iron(III) octakis(perfluorophenyl)tetraazaporphyrin μ-oxodimer: a highly efficient catalyst for biomimetic oxygenation reactions

Detalhes bibliográficos
Parent link:Tetrahedron Letters: The International Journal for the Rapid Publication of all Preliminary Communications in Organic Chemistry
Vol. 55, iss. 41.— 2014.— [P. 5687-5690]
Autor Corporativo: Национальный исследовательский Томский политехнический университет Институт природных ресурсов Кафедра технологии органических веществ и полимерных материалов
Outros Autores: Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Celik С., Geraskina М. R., Yoshimura A. Akira, Zhdankin V. V. Viktor Vladimirovich, Nemykin V. N.
Resumo:Title screen
Binuclear iron(III) octakis(perfluorophenyl)tetraazaporphyrin μ-oxodimer complex was prepared by the reaction of bis(perfluorophenyl)maleonitrile and Fe(CO)5and tested in catalytic oxygenation reactions of several hydrocarbons in comparison with the analogous non-fluorinated phthalocyanine complexes. Results of the study demonstrate that this complex is a highly efficient catalyst for the oxygenation of anthracene, 2-tert-butylanthracene, naphthalene, 2-methylnaphthalene, phenanthrene, adamantane, and toluene using iodosylbenzene, oligomeric iodosylbenzene sulfate, or Oxone as stoichiometric oxidants.
Режим доступа: по договору с организацией-держателем ресурса
Publicado em: 2014
Assuntos:
электронный ресурс
труды учёных ТПУ
синтез
свойства
оксигенирование
углеводороды
перфторфенил
октакис
Acesso em linha:http://dx.doi.org/10.1016/j.tetlet.2014.08.070
Formato: Recurso Electrónico Capítulo de Livro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=650131
Descrição
Resumo:Title screen
Binuclear iron(III) octakis(perfluorophenyl)tetraazaporphyrin μ-oxodimer complex was prepared by the reaction of bis(perfluorophenyl)maleonitrile and Fe(CO)5and tested in catalytic oxygenation reactions of several hydrocarbons in comparison with the analogous non-fluorinated phthalocyanine complexes. Results of the study demonstrate that this complex is a highly efficient catalyst for the oxygenation of anthracene, 2-tert-butylanthracene, naphthalene, 2-methylnaphthalene, phenanthrene, adamantane, and toluene using iodosylbenzene, oligomeric iodosylbenzene sulfate, or Oxone as stoichiometric oxidants.
Режим доступа: по договору с организацией-держателем ресурса
DOI:10.1016/j.tetlet.2014.08.070

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