Binuclear iron(III) octakis(perfluorophenyl)tetraazaporphyrin μ-oxodimer: a highly efficient catalyst for biomimetic oxygenation reactions

Binuclear iron(III) octakis(perfluorophenyl)tetraazaporphyrin μ-oxodimer: a highly efficient catalyst for biomimetic oxygenation reactions

Bibliographic Details
Parent link:	Tetrahedron Letters: The International Journal for the Rapid Publication of all Preliminary Communications in Organic Chemistry Vol. 55, iss. 41.— 2014.— [P. 5687-5690]
Corporate Author:	Национальный исследовательский Томский политехнический университет Институт природных ресурсов Кафедра технологии органических веществ и полимерных материалов
Other Authors:	Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Celik С., Geraskina М. R., Yoshimura A. Akira, Zhdankin V. V. Viktor Vladimirovich, Nemykin V. N.
Summary:	Title screen Binuclear iron(III) octakis(perfluorophenyl)tetraazaporphyrin μ-oxodimer complex was prepared by the reaction of bis(perfluorophenyl)maleonitrile and Fe(CO)5and tested in catalytic oxygenation reactions of several hydrocarbons in comparison with the analogous non-fluorinated phthalocyanine complexes. Results of the study demonstrate that this complex is a highly efficient catalyst for the oxygenation of anthracene, 2-tert-butylanthracene, naphthalene, 2-methylnaphthalene, phenanthrene, adamantane, and toluene using iodosylbenzene, oligomeric iodosylbenzene sulfate, or Oxone as stoichiometric oxidants. Режим доступа: по договору с организацией-держателем ресурса
Published:	2014
Subjects:	электронный ресурс труды учёных ТПУ синтез свойства оксигенирование углеводороды перфторфенил октакис
Online Access:	http://dx.doi.org/10.1016/j.tetlet.2014.08.070
Format:	Electronic Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=650131

Internet

http://dx.doi.org/10.1016/j.tetlet.2014.08.070