Highly efficient RuCl[3]-catalyzed disproportionation of (diacetoxyiodo)benzene to iodylbenzene and iodobenzene; leading to the efficient oxidation of alcohols to carbonyl compounds

Bibliographic Details
Parent link:	Tetrahedron Letters: The International Journal for the Rapid Publication of all Preliminary Communications in Organic Chemistry Vol. 47, iss. 35.— 2006.— [P. 6305-6308]
Other Authors:	Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Chi Ki-Whan, Park Joo Yeon, Karimov R., Zhdankin V. V. Viktor Vladimirovich
Summary:	Title screen (Diacetoxyiodo)benzene (DIB) selectively oxidizes primary and secondary alcohols to the respective carbonyl compounds in the presence of RuCl3 (0.8–1.0 mol %) at room temperature in aqueous acetonitrile. This reaction proceeds via an initial instantaneous Ru-catalyzed disproportionation of DIB to iodobenzene and iodylbenzene with the latter acting as the actual stoichiometric oxidant toward alcohols. Режим доступа: по договору с организацией-держателем ресурса
Language:	English
Published:	2006
Subjects:	электронный ресурс труды учёных ТПУ окисление спектры карбонильные соединения синтез иодил бензол окислитель рутений катализаторы бензол
Online Access:	http://dx.doi.org/10.1016/j.tetlet.2006.06.100
Format:	Electronic Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=650110

Internet