Preparation and structure of oligomeric iodosylbenzene sulfate (PhIO)[3]·SO[3]: stable and water-soluble analog of iodosylbenzene; European Journal of Organic Chemistry; Vol. 2007, iss. 27
| Источник: | European Journal of Organic Chemistry Vol. 2007, iss. 27.— 2007.— [P. 4475-4478] |
|---|---|
| Другие авторы: | , , , , , |
| Примечания: | Title screen New phenyliodine(III) sulfate (PhIO)3·SO3, which has a complex polymeric structure of the trimeric iodosylbenzene units linked by sulfate anions, can be conveniently prepared by treatment of (diacetoxy)iodobenzene with sodium bisulfate in the presence of water. This sulfate can find practical application as a readily available, stable, and water-soluble hypervalent iodine reagent with a reactivity pattern similar to that of iodosylbenzene. |
| Язык: | английский |
| Опубликовано: |
2007
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| Предметы: | |
| Online-ссылка: | http://dx.doi.org/10.1002/ejoc.200700625 |
| Формат: | Электронный ресурс Статья |
| Запись в KOHA: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=650104 |
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| 200 | 1 | |a Preparation and structure of oligomeric iodosylbenzene sulfate (PhIO)[3]·SO[3]: stable and water-soluble analog of iodosylbenzene |f A. Y. Koposov [et al.] | |
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| 300 | |a Title screen | ||
| 320 | |a [References: p. 4478 (12 tit.)] | ||
| 330 | |a New phenyliodine(III) sulfate (PhIO)3·SO3, which has a complex polymeric structure of the trimeric iodosylbenzene units linked by sulfate anions, can be conveniently prepared by treatment of (diacetoxy)iodobenzene with sodium bisulfate in the presence of water. This sulfate can find practical application as a readily available, stable, and water-soluble hypervalent iodine reagent with a reactivity pattern similar to that of iodosylbenzene. | ||
| 461 | |t European Journal of Organic Chemistry | ||
| 463 | |t Vol. 2007, iss. 27 |v [P. 4475-4478] |d 2007 | ||
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