Preparation and structure of oligomeric iodosylbenzene sulfate (PhIO)[3]·SO[3]: stable and water-soluble analog of iodosylbenzene; European Journal of Organic Chemistry; Vol. 2007, iss. 27

Detalles Bibliográficos
Parent link:European Journal of Organic Chemistry
Vol. 2007, iss. 27.— 2007.— [P. 4475-4478]
Outros autores: Koposov A. Y., Netzel B. C., Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Nemykin V. N., Nazarenko A. Y., Zhdankin V. V. Viktor Vladimirovich
Summary:Title screen
New phenyliodine(III) sulfate (PhIO)3·SO3, which has a complex polymeric structure of the trimeric iodosylbenzene units linked by sulfate anions, can be conveniently prepared by treatment of (diacetoxy)iodobenzene with sodium bisulfate in the presence of water. This sulfate can find practical application as a readily available, stable, and water-soluble hypervalent iodine reagent with a reactivity pattern similar to that of iodosylbenzene.
Idioma:inglés
Publicado: 2007
Subjects:
Acceso en liña:http://dx.doi.org/10.1002/ejoc.200700625
Formato: Electrónico Capítulo de libro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=650104

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200 1 |a Preparation and structure of oligomeric iodosylbenzene sulfate (PhIO)[3]·SO[3]: stable and water-soluble analog of iodosylbenzene  |f A. Y. Koposov [et al.] 
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300 |a Title screen 
320 |a [References: p. 4478 (12 tit.)] 
330 |a New phenyliodine(III) sulfate (PhIO)3·SO3, which has a complex polymeric structure of the trimeric iodosylbenzene units linked by sulfate anions, can be conveniently prepared by treatment of (diacetoxy)iodobenzene with sodium bisulfate in the presence of water. This sulfate can find practical application as a readily available, stable, and water-soluble hypervalent iodine reagent with a reactivity pattern similar to that of iodosylbenzene. 
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463 |t Vol. 2007, iss. 27  |v [P. 4475-4478]  |d 2007 
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