Preparation and structure of oligomeric iodosylbenzene sulfate (PhIO)[3]·SO[3]: stable and water-soluble analog of iodosylbenzene

Bibliographic Details
Parent link:European Journal of Organic Chemistry
Vol. 2007, iss. 27.— 2007.— [P. 4475-4478]
Other Authors: Koposov A. Y., Netzel B. C., Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Nemykin V. N., Nazarenko A. Y., Zhdankin V. V. Viktor Vladimirovich
Summary:Title screen
New phenyliodine(III) sulfate (PhIO)3·SO3, which has a complex polymeric structure of the trimeric iodosylbenzene units linked by sulfate anions, can be conveniently prepared by treatment of (diacetoxy)iodobenzene with sodium bisulfate in the presence of water. This sulfate can find practical application as a readily available, stable, and water-soluble hypervalent iodine reagent with a reactivity pattern similar to that of iodosylbenzene.
Published: 2007
Subjects:
Online Access:http://dx.doi.org/10.1002/ejoc.200700625
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=650104