Preparation and structure of oligomeric iodosylbenzene sulfate (PhIO)[3]·SO[3]: stable and water-soluble analog of iodosylbenzene

Opis bibliograficzny
Parent link:European Journal of Organic Chemistry
Vol. 2007, iss. 27.— 2007.— [P. 4475-4478]
Kolejni autorzy: Koposov A. Y., Netzel B. C., Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Nemykin V. N., Nazarenko A. Y., Zhdankin V. V. Viktor Vladimirovich
Streszczenie:Title screen
New phenyliodine(III) sulfate (PhIO)3·SO3, which has a complex polymeric structure of the trimeric iodosylbenzene units linked by sulfate anions, can be conveniently prepared by treatment of (diacetoxy)iodobenzene with sodium bisulfate in the presence of water. This sulfate can find practical application as a readily available, stable, and water-soluble hypervalent iodine reagent with a reactivity pattern similar to that of iodosylbenzene.
Język:angielski
Wydane: 2007
Hasła przedmiotowe:
Dostęp online:http://dx.doi.org/10.1002/ejoc.200700625
Format: Elektroniczne Rozdział
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=650104