Preparation and structure of oligomeric iodosylbenzene sulfate (PhIO)[3]·SO[3]: stable and water-soluble analog of iodosylbenzene
| Parent link: | European Journal of Organic Chemistry Vol. 2007, iss. 27.— 2007.— [P. 4475-4478] |
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| その他の著者: | , , , , , |
| 要約: | Title screen New phenyliodine(III) sulfate (PhIO)3·SO3, which has a complex polymeric structure of the trimeric iodosylbenzene units linked by sulfate anions, can be conveniently prepared by treatment of (diacetoxy)iodobenzene with sodium bisulfate in the presence of water. This sulfate can find practical application as a readily available, stable, and water-soluble hypervalent iodine reagent with a reactivity pattern similar to that of iodosylbenzene. |
| 言語: | 英語 |
| 出版事項: |
2007
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| 主題: | |
| オンライン･アクセス: | http://dx.doi.org/10.1002/ejoc.200700625 |
| フォーマット: | 電子媒体 図書の章 |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=650104 |
| 要約: | Title screen New phenyliodine(III) sulfate (PhIO)3·SO3, which has a complex polymeric structure of the trimeric iodosylbenzene units linked by sulfate anions, can be conveniently prepared by treatment of (diacetoxy)iodobenzene with sodium bisulfate in the presence of water. This sulfate can find practical application as a readily available, stable, and water-soluble hypervalent iodine reagent with a reactivity pattern similar to that of iodosylbenzene. |
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| DOI: | 10.1002/ejoc.200700625 |