Preparation and structure of oligomeric iodosylbenzene sulfate (PhIO)[3]·SO[3]: stable and water-soluble analog of iodosylbenzene; European Journal of Organic Chemistry; Vol. 2007, iss. 27

ग्रंथसूची विवरण
Parent link:European Journal of Organic Chemistry
Vol. 2007, iss. 27.— 2007.— [P. 4475-4478]
अन्य लेखक: Koposov A. Y., Netzel B. C., Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Nemykin V. N., Nazarenko A. Y., Zhdankin V. V. Viktor Vladimirovich
सारांश:Title screen
New phenyliodine(III) sulfate (PhIO)3·SO3, which has a complex polymeric structure of the trimeric iodosylbenzene units linked by sulfate anions, can be conveniently prepared by treatment of (diacetoxy)iodobenzene with sodium bisulfate in the presence of water. This sulfate can find practical application as a readily available, stable, and water-soluble hypervalent iodine reagent with a reactivity pattern similar to that of iodosylbenzene.
भाषा:अंग्रेज़ी
प्रकाशित: 2007
विषय:
ऑनलाइन पहुंच:http://dx.doi.org/10.1002/ejoc.200700625
स्वरूप: इलेक्ट्रोनिक पुस्तक अध्याय
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=650104
विवरण
सारांश:Title screen
New phenyliodine(III) sulfate (PhIO)3·SO3, which has a complex polymeric structure of the trimeric iodosylbenzene units linked by sulfate anions, can be conveniently prepared by treatment of (diacetoxy)iodobenzene with sodium bisulfate in the presence of water. This sulfate can find practical application as a readily available, stable, and water-soluble hypervalent iodine reagent with a reactivity pattern similar to that of iodosylbenzene.
डिजिटल ऑब्जेक्ट पहचानकर्ता:10.1002/ejoc.200700625