Oxidative Cycloaddition of Aldoximes with Maleimides using Catalytic Hydroxy(aryl)iodonium Species

Oxidative Cycloaddition of Aldoximes with Maleimides using Catalytic Hydroxy(aryl)iodonium Species

Bibliographic Details
Parent link:	Advanced Synthesis and Catalysis Vol. 358, iss. 14.— 2016.— [P. 2340-2344]
Corporate Author:	Национальный исследовательский Томский политехнический университет Институт природных ресурсов Кафедра технологии органических веществ и полимерных материалов
Other Authors:	Yoshimura A. Akira, Khiem C. Nguyen, Gregory T. Rohde, Akio Saito, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Zhdankin V. V. Viktor Vladimirovich
Summary:	Заглавие с экрана A mild catalytic procedure for the efficient oxidative cyclization of aldoximes with maleimides mediated by hypervalent iodine(III) active species has been developed. This catalytic cyclization affords the corresponding pyrrolo-isoxazole products in generally good yields. The catalytic cycle involves active hydroxy(aryl)iodonium species generatedin situ from 2-iodobenzoic acid as precatalyst and m-chloroperoxybenzoic acid (m-CPBA) as terminal oxidant in the presence of trifluoromethanesulfonic acid. The presence of active hydroxy(aryl)iodonium species in this reaction has been confirmed by ESI-mass spectrometry and 1H NMR spectroscopy. Режим доступа: по договору с организацией-держателем ресурса
Published:	2016
Subjects:	электронный ресурс труды учёных ТПУ синтез катализ иодоний циклизация окисление
Online Access:	http://dx.doi.org/10.1002/adsc.201600331
Format:	Electronic Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=649133

Internet

http://dx.doi.org/10.1002/adsc.201600331