Quantum chemical study of the structure and properties of isotopically pure lead chalcogenides

Bibliographic Details
Parent link:IOP Conference Series: Materials Science and Engineering
Vol. 112 : Fundamental Aspects of Rare-earth Elements Mining and Separation and Modern Materials Engineering (REES-2015).— 2016.— [012022, 9 p.]
Corporate Authors: Национальный исследовательский Томский политехнический университет (ТПУ) Физико-технический институт (ФТИ) Кафедра химической технологии редких, рассеянных и радиоактивных элементов (№ 43) (ХТРЭ), Национальный исследовательский Томский политехнический университет (ТПУ) Юргинский технологический институт (филиал) (ЮТИ) Кафедра естественного научного образования (ЕНО)
Other Authors: Poleshchuk O. Kh. Oleg Khemovich, Egorov N. B. Nikolai Borisovich, Akimov D. V. Dmitry Vasilievich, Zherin (Gerin) I. I. Ivan Ignatyevich, Zhuravlev N. A.
Summary:Title screen
In the present work the theoretical methods B3LYP/SDD, GGA and BP86/TZ2P were used for quantum-chemical calculations of lead chalcogenides. It is shown that these levels of theory are applicable for assessment of their geometric parameters, Raman and IR spectra and thermodynamic characteristics. It is shown that there are correlations between the experimental and calculated characteristics of lead sulphide, selenide and telluride. The influence of different isotopes of lead, sulphur, selenium and tellurium on the thermodynamic parameters and the Raman spectra for the lead chalcogenides is shown.
Режим доступа: по договору с организацией-держателем ресурса
Published: 2016
Subjects:
Online Access:http://dx.doi.org/10.1088/1757-899X/112/1/012022
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=648406