Influence of Ultra-Violet Radiation on Sublimation Energy of Silver Chloride (AgCl)

Bibliographic Details
Parent link:Key Engineering Materials: Scientific Journal.— , 1982-
Vol. 685 : High Technology: Research and Applications 2015 (HTRA 2015).— 2016.— [P. 735-738]
Main Author: Mostovshchikov A. V. Andrey Vladimirovich
Corporate Author: Национальный исследовательский Томский политехнический университет (ТПУ) Институт физики высоких технологий (ИФВТ) Кафедра общей химии и химической технологии (ОХХТ)
Other Authors: Ilyin A. P. Aleksandr Petrovich, Barabash N. S.
Summary:Title screen
Influence of silver chloride synthesis conditions on its heat of sublimation after ultra-violet irradiation was explored. It was determined that silver chloride synthesized in excess of silver ions after irradiation was characterized by heat of sublimation about 6813 J/g, which meant that the original value increased in ~ 1.8 times. At the same time silver chloride synthesized in excess of chloride ions was characterized by decrease in value of heat of sublimation by ~ 2 times. Growth of heat of sublimation of silver chloride with excess of silver ions is connected with energy expenditure on sublimation due to decrease in proportion of surface which is not covered with silver. Reduction of heat of sublimation of silver chloride with excess of chloride ions is explained by absence of silver solid surface film and catalytic effect of silver klasters formed during the process of irradiation.
Режим доступа: по договору с организацией-держателем ресурса
Language:English
Published: 2016
Series:Chemical Engineering and Technology
Subjects:
Online Access:http://dx.doi.org/10.4028/www.scientific.net/KEM.685.735
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=646527