RbBrF4 Revisited

Bibliographic Details
Parent link:Zeitschrift für anorganische und allgemeine Chemie (ZAAC)
Vol. 641, iss. 15.— 2015.— [P. 2593-2598]
Corporate Author: Национальный исследовательский Томский политехнический университет (ТПУ) Научно-исследовательский институт высоких напряжений (НИИВН) Лаборатория № 7
Other Authors: Ivlev S. I. Sergey Ivanovich, Karttunen A. J. Antti, Ostvald R. V. Roman Vyacheslavovich, Kraus F. F. Florian
Summary:Title screen
Rubidium tetrafluoridobromate(III) was synthesized and structurally characterized. The compound is isotypic to sodium and potassium tetrafluoridobromate(III), and crystallizes in the tetragonal space group I4/mcm (tI24, KBrF4 structure type) with a = 6.3718(2), c = 11.4934(3) Å, V = 466.63(2) Å3, Z = 4, at T = 293 K. Additionally we investigated the compound by means of IR and Raman spectroscopy as well as theoretical studies. The data obtained by quantum chemical calculations confirm the crystal structure, and also the atomic distances and angles with an average deviation of 2.2 to 2.7 %.
Language:English
Published: 2015
Subjects:
Online Access:http://dx.doi.org/10.1002/zaac.201500647
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=645411