Thermodynamic Analysis of Catalytic Cracking Reactions as the First Stage in the Development of Mathematical Description

Bibliographic Details
Parent link:Procedia Chemistry
Vol. 15 : Chemistry and Chemical Engineering in XXI century (CCE 2015).— 2015.— [P. 342-349]
Corporate Author: Национальный исследовательский Томский политехнический университет (ТПУ) Институт природных ресурсов (ИПР) Кафедра химической технологии топлива и химической кибернетики (ХТТ)
Other Authors: Nazarova G. Yu. Galina Yurievna, Ivanchina E. D. Emilia Dmitrievna, Ivashkina E. N. Elena Nikolaevna, Kiseleva S. Svetlana, Stebeneva V. Valeria
Summary:Title screen
In this work thermodynamic analysis of catalytic cracking reaction involving the high molecular weight hydrocarbons was carried out using quantum chemical method of calculation realized in Gaussian software. The method of calculation is DFT (Density Functional Theory), theoretical approximation is B3LYP model, 3-21G basis. The list of catalytic cracking reactions for calculation was prepared on the basis of the theoretical data about catalytic cracking, laboratory and experimental data from the industrial unit. The enthalpy and Gibbs energy values of the main catalytic cracking reactions are presented under the process conditions. The results of this work will be used to develop a kinetic model of catalytic cracking of petroleum feedstock.
Режим доступа: по договору с организацией-держателем ресурса
Language:English
Published: 2015
Subjects:
Online Access:http://dx.doi.org/10.1016/j.proche.2015.10.054
http://earchive.tpu.ru/handle/11683/15074
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=645401