Electrochemical Determination of Some Triphenylmethane Dyes by Means of Voltammetry

Bibliographic Details
Parent link:Procedia Chemistry
Vol. 15 : Chemistry and Chemical Engineering in XXI century (CCE 2015).— 2015.— [P. 109-114]
Corporate Author: Национальный исследовательский Томский политехнический университет (ТПУ) Институт природных ресурсов (ИПР) Кафедра физической и аналитической химии (ФАХ)
Other Authors: Vishenkova D. A. Dariya Aleksandrovna, Korotkova E. I. Elena Ivanovna, Sokolova V. A. Vera Alekseevna, Kratochvil B.
Summary:Title screen
This paper provides the investigation of electrochemical properties of triphenylmethane dyes using a voltammetric method with constant-current potential sweep. Malachite green (MG) and basic fuchsin (BF) have been chosen as representatives of the triphenylmethane dyes. The electrochemical behavior of MG and BF on the surface of a mercury-film electrode depending on рН, the nature of background electrolyte and scan rate of potential sweep have been investigated. The conditions of registration have been determined for MG and BF detecting in the solution. It is demonstrated that the reduction peak currents of MG and BF increase linearly with their concentration in the range of 9.0·10{-5}- 7.0·10{-3} mol/dm{3} for MG, 6.0·10{-5} - 8.0 10{-3} mol/dm3 for BF with correlation coefficients of 0.9987 and 0.9961, respectively. The detection limit of MG is 5.0·10{-5} mol/dm{3} and for BF - 2.0·10{-5} mol/dm{3}.
Режим доступа: по договору с организацией-держателем ресурса
Language:English
Published: 2015
Subjects:
Online Access:http://dx.doi.org/10.1016/j.proche.2015.10.017
http://earchive.tpu.ru/handle/11683/14879
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=645329