Formation Regularities of AlOOH Hollow Spheres during Aluminum Nanopowder Water Oxidation

書目詳細資料
Parent link:AIP Conference Proceedings
Vol. 1683 : Advanced Materials with Hierarchical Structure for New Technologies and Reliable Structures.— 2015.— [020127, 5 p.]
其他作者: Lozhkomoev A. S. Aleksandr Sergeevich, Glazkova E. A. Elena Alekseevna, Svarovskaya N. V. Natalia Valentinovna, Bakina O. V. Olga Vladimirovna, Kazantsev S. O. Sergey Olegovich, Lerner M. I. Marat Izrailyevich
總結:Title screen
There described a novel environmentally friendly synthesis route of micro/nanostructured hollow spheres of AlOOH by oxidation of Al nanopowder in pure water under mild processing conditions. The reaction kinetics of the aluminum nanopowder interaction with water was studied using the method of continuous recording of suspension pH and temperature. There observed the change in Al{3+} concentration in the reaction medium and the rate of hydrogen release as well as TEM investigations of the intermediate reaction products at different stages of the process were performed. It is shown that AlOOH hollow spheres are formed through the aluminum core dissolution, Al{3+} ion diffusion through the surface oxide film and AlOOH nanosheets formation on the surface of the precursor oxide film.
Режим доступа: по договору с организацией-держателем ресурса
語言:英语
出版: 2015
主題:
在線閱讀:http://dx.doi.org/10.1063/1.4932817
格式: 電子 Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=644959